fetic体系原位合成ticfe的热力学和动力学分析word格式论文.docx

优秀毕业论文 精品参考文献资料 STUDY ON THERMODYNAMICS AND KINETICS IN-SITU SYNTHESIS TiC/Fe IN Fe - Ti - C SYSTEM ABSTRACT In-situ synthesis method is a kind of good method to prepare good performance composite material, characteristic of the preparation of composite material can increase the body surface no pollution, good matrix and enhance body intermiscibility , the higher interface bonding strength and so on, so application is very extensive. The TiC is performance better compound, due to its lattice structure, make it has high hardness, high melting point, wear resistance and good thermal stability etc, it can be applied in many fields. This paper first uses XD method to study the Fe - Ti - C system synthesis TiC/Fe composite material, through the research of the thermodynamics and Kinetics, knowledge of the specific reaction process, and various factors on composite material morphology, microstructure, properties of the effect,and then study the legal system for powder metallurgy TiCp/Fe composite material, and then and studied the application of laser cladding. Through the Fe - Ti - C system synthesis TiC/Fe composite material thermodynamics analysis shows that the Fe - Ti - C system may be some product mainly has TiC, Fe3C, FeTi, Fe2Ti, the possibility of products: TiC Fe2Ti FeTi Fe3C, when n (Ti) : n (C) = 1:1, Ti and C can just completely TiC formation, and no other product; When n (Ti) : n (C) ≠1:1, when C excess, the product has not only TiC, but also Fe3C, when Ti excess, the product is TiC and Fe2Ti, but generate FeTi can be very small. Through the Fe - Ti - C system synthesis TiC/Fe composite Kinetics analysis that the system of reaction process is α-Fe into reported γ-Fe in 760℃ and 918℃ at first. Then Fe and Ti or so reaction formation Fe2Ti in 1150℃, finally C and Fe2Ti or so reaction generating TiC in 1158℃, through calculation indicated that the formation Fe2Ti reaction activation energy E * = 80 KJ/mol, formation of the TiC reaction activation energy E *