fe3o4纳米颗粒及其复合材料的制备与性能分析word格式论文.docx

摘要近年来，由于磁性 Fe3O4 纳米颗粒及其复合材料在磁流体、吸波材料及生物医学方面等领 域潜在的应用价值而引起了广泛关注和研究。本文采用简单的溶剂热法制备了尺寸可控的空心 Fe3O4 纳米颗粒，利用 XRD、SEM、TEM、FT-IR 和穆斯堡尔谱对其形貌和结构进行了研究， 并采用振动样品磁强计和矢量网络分析仪研究了其磁性能及电磁参数；采用改进的 St?ber 法制 备了 Fe3O4@SiO2 纳米核壳结构，提高了 Fe3O4 的稳定性，将核壳结构在高温下还原得到 Fe@SiO2 和 Fe/Fe3O4@SiO2 复合材料；论文还采用不同的方法制备了 Fe3O4/GNS 复合材料，采用振动样 品磁强计和矢量网络分析仪分别研究了复合材料的磁性能及其电磁波吸收性能。通过加入不同的结构引导剂利用溶剂热法制备出了尺寸在 200~400nm 的空心 Fe3O4 纳米 球，研究发现，空心 Fe3O4 纳米球颗粒尺寸与饱和磁化强度（Ms）成反比，当尺寸为 200nm 时 达到最大的 Ms 值 87.4emu/g，具有空心结构的样品的最大反射损耗率出现在 8~9 GHz；通过控 制不同的实验条件制备了核壳结构的 Fe3O4@SiO2 纳米复合粒子，并且在氢气氛下还原制得 Fe@SiO2 复合材料，还原后的复合材料稳定性强，在较宽的测试频段内均具有较大的反射损耗 但反射损耗的最佳厚度较大；以乙酰丙酮铁为铁源，溶剂热法原位复合法制得的 Fe3O4/GNS 复 合材料中，Fe3O4 颗粒具有较好的分散性，M 较低，但复合材料的吸收频带增大、反射损耗值 减小。关键词：溶剂热，Fe3O4 铁氧体，电磁波吸波性能，复合材料，磁性颗粒，热还原ABSTRACTIn recent years, Fe3O4 ferrite especially magnetic Fe3O4 nanomaterials and its composites have attracted more attentions and studies because of its potential applications in ferrofluid, magnetic absorbing material and biomedicine. Hollow structured magnetite spheres with various sizes were fabricated by a simple solvothermal process. The morphology and crystal structures of the products were characterized by X-ray diffraction (XRD), emission scanning electron microscope (SEM) and transmission electron microscopy (TEM), respectively, and the vibration sample magnetometer(VSM), FT-IR and m?ssbauer were used to study the magnetic properties. The electromagnetic(EM) absorbing performance wave also studied. The Fe3O4@SiO2 nanoparticles with core-shell structure were prepared with the improved st?ber and improved the Fe3O4 oxide stability, under a high temperature with reducing gas, the composite materials can convert to Fe@SiO2 and Fe/Fe3O4@SiO2 materials; Fe3O4/GNS composite materials were aiso prepared with different synthetic methods. The magnetic properties and EM absorbing performance were investigated by VSM and vector network analyzer.Hollow structured Fe3O4 naonospheres were successfully synthesised by the solvothermal process, with the assistance of