基于吡咯并吡咯烷酮结构的窄带隙小分子液晶调控p3htzno杂化本体异质结微观形貌及其性能优化-micro - morphology and performance optimization of p3 htz no hybrid heterojunction controlled by narrow band gap small molecule liquid crystal based on pyrrolopyrrolidone structure.docxVIP

Abstractbetter dispersion of ZnO in organic phase. Interestingly, upon thermal annealing treatment at 140°C (mesomorphase temperature), the enhancement in crystallinity and ordering of the P3HT polymer chain is induced by self-assembly behavior of DPP-TP6 liquid crystalline molecules, improving the orderness of P3HT/ZnO bulk-heterojunction and offering a more efficient path for carrier transport. Meanwhile, induced by the liquid crystals ordering, the micromophology of P3HT/ZnO hybrid system is also improved and nanoscale microphase separation is obtained. On this basis, the PCE of P3HT/ZnO hybrid solar cells is improved mainly due to the increase of short circuit current density (Jsc) and fill factor (FF). Furthermore, absorption enhancement caused by narrow bandgap liquid crystal DPP-TP6 can also contribute to the increase of Jsc. Overall, introducing narrow bandgap liquid crystal into P3HT/ZnO is a efficient approach to optimize micromophology of hybrid thin film and improve solar cell device performance.Key words: hybrid solar cells; micromophology; liquid crystals; self-assembly目录第 1 章 绪论 ................................................................................................................. 11.1 引言 ................................................................................................................. 11.2 有机/无机杂化太阳能电池 ............................................................................ 21.2.1有机/无机杂化太阳能电池的结构及工作原理 ................................ 21.2.2有机/无机杂化太阳能电池光伏性能参数 ........................................ 51.3 有机/无机杂化太阳能电池活性层微观形貌调控策略 ................................ 71.3.1改变活性层溶剂和热退火处理 ......................................................... 71.3.2无机半导体纳米晶尺寸和形态控制 ................................................. 81.3.3无机半导体纳米晶表面改性 ............................................................. 91.3.4在共轭聚合物中原位生长无机半导体纳米晶 ............................... 121.3.5引入自组装特性的物质 ............................................................