基于氮气气浮除油与改善煤化工废水生化处理效能分析-analysis of oil removal by nitrogen floatation and improvement of biochemical treatment efficiency of coal chemical wastewater.docxVIP

知PACT 工艺对COD和总酚的去除效果要优于SBR 工艺。另外，PACT 工艺的抗有机负荷冲击能力要优于SBR 工艺。氮气气浮和PACT 工艺联合运行出水COD 和总酚浓度分别为169.28±22.43%和17.79±3.93%。扫描电镜发现PACT 系统活性污泥微生物量大，起主要处理效果的优势菌种为杆状菌。关键词：煤化工废水；除油；氮气气浮；SBR；PACTAbstractCoalchemicalwastewaterisrecalcitranttoxicwastewater,becauseofthepoor biodegradabilityithasbeenaproblemtotreatcoalchemicalwastewater.Theoilinthe wastewateralsocauseddifficultiesincoalchemicalwastewatertreatmentandisthe maincauseoffoam.Thus,ithasastrongpracticalsignificancetoresearchthe degreasingpretreatmentof coal chemical wastewater.Thisstudyinvestigatedthedegreasingeffectofoil-separatingtank,coarsegraining method,coagulation-sedimentationandairflotationmethod,anddeterminedthe optimaldegreasingprocessanditsoptimumoperatingparameters.Experimentalresults showedthatairflotationwasthebestdegreasingmethod,andwhentheflotation residencetimeof10min,theairinflowrateof0.2m3/h,PACdosageof100mg/L,PAM dosageof2mg/L,andnoadjustmentofthepHofrawwater,theflotationwithairand nitrogencouldachievebetterremovalratesforoil,CODandtotalphenol,whichwere58.25%,41.23%and46.3%respectively.Comparedairflotationandnitrogenflotation, theremovalperformanceofoil,COD,andtotalphenolwasalmostnodifference,but thebiodegradabilityofeffluentofairflotationwastewaterwoulddeteriorate,andthe nitrogenflotationcouldimprovewastewaterbiodegradability.TheB/Cvalueofraw waterwasabout0.28,whichbelongedtorefractorywastewater;afterairflotationthe B/Cvalueoftheeffluentreducedtoabout0.25anditincreasedto0.30orsoafter nitrogenflotation.WithGC-MSinstrumentanalysisofrawwater,effluentofnitrogen flotationandairflotation,itshowedthatnitrogenflotationhadlittleeffectonorganic typesofwastewater,butafterairflotation,morecyclopentenone,pyridinederivatives, otherheterocyclicaromatichydrocarbonsandbenzenederivativesweredetected,which is themain cause of thebiodegradabilityreduction ofwastewater.ThetreatmenteffectofnitrogenandairflotationonthesubsequentSBRsystem wasinvestigated.WhenSBRreactortemperaturewas25℃,theprocessingcyclewas24h,theconcentratio