电解液组成对锂离子电池碳负极SEI膜性能的影响.pdf

第 32 卷 　第 6 期 电　　　池 Vol. 32 , No. 6 2002 年 　　12 月 BA TTER Y 　BIMON THL Y Dec ,2002 　 电解液组成对锂离子电池碳负极 SEI 膜性能的影响 1 ,2 1 2 袁中直 ,周震涛 ,李伟善 ( 1 华南理工大学材料科学与工程学院 ,广东 广州 　510641 ; 2 华南师范大学化学系 ,广东 广州 　510631) 摘要 :综述了液态锂离子二次电池中 , 电解液组成包括电解质盐、溶剂特别是电解液添加剂对碳负极 SEI 膜性能的影响 ,还 叙述了改进电极/ 溶液界面反应的电极表面预成膜方法等。对影响 SEI 膜的机理作了分析。 关键词 :锂离子电池 ; 　电解液 ; 　碳负极 ; 　SEI 膜 ( ) 中图分类号: TM9129 　　文献标识码 :A 　　文章编号 : 1001 - 1579 2002 06 - 0354 - 04 Effects of electrolyte compositions on performances of SEI on graphite electrode of Liion battery YUAN Zhongzhi1 ,2 ,ZHOU Zhentao 1 ,L I Weishan2 ( 1Institute of M aterials Science and Engineering , South China U niversity of Technology , Guangz hou , Guangdong 510641 , China ; ) 2 Depart ment of Chemist ry , South China Norm al U niversity , Guangdong , Guangz hou , 510631 , China Abstract : The effects of electrolyte compositions including electrolyte salts ,solvents and the inorganic/ organic additives on the performance of SEI film were reviewedThe film formed on the surface of negative graphite electrode had important influences on the cycling life ,reversible capacity ,selfdischarge and electrode polarization of Liion batteryThe mechanisms of the effects hap pened were discussedThe electrode surface modifications which influenced the interact