合金化元素对ti-nb基合金的显微组织和相关性能的影响-influence of alloying elements on microstructure and related properties of ti - nb based alloys.docx

AbstractTi-Nb alloys have the advantages of low elastic modulus, super-elastic and shape memory properties, which exhibit a great application potential as a biological graft material. The existing results show that the microstructure and mechanical properties of Ti-Nb alloys mainly depend on the composition of the alloy. The performance of the alloy can be improved significantly by appropriate alloying. In this thesis, the effects of the additions of Zr, Mo and Si alloying element on the microstructure, mechanical properties and corrosion resistance of Ti-22Nb alloy were studied and the impact mechanism were discussed. The purpose is to provide the theoretical and experimental guideline for the experiment of mechanical properties by alloying method. The main results are as follows:The results show that the solid solution of Ti-22Nb alloy is mainly composed of acicular martensite α and β phase, While, the Ti-Nb-Zr alloy and Ti-Nb-Mo alloys is composed of a single β phase, the additions of Zr and Mo elements hinder the formation of α phase during the quenching process. A small amount of Si element can stabilize the β phase, when the content of Si element is 2-4 at.%, the solution-treated Ti-Nb-Si alloy is composed of single β phase. When the content of Si element is about 6 at.%, some intermetallic compounds can form in the alloy;The results of room temperature tensile test show that the addition of Zr element can improve the mechanical properties of Ti-22Nb alloy after solutiontreatment of 800 ℃. With the addition of Zr element, the strength and the elongation ofthe Ti-Nb-Zr alloys increases, and the Ti-22Nb-6Zr alloy has a maximum tensile strength of 700 MPa with the maximum elongation of 46.5%. In the solution-treated Ti-Nb-Mo alloy, Ti-22Nb-2Mo alloy has the greatest tensile strength and elongation, it’s 648 MPa and 33% respectively. During the tensile test Ti-22Nb-4Mo and Ti-22Nb-6Mo alloy does not appear work harden, showing the characteristics of rubb