快淬态lamgni3.6m0.4m=ni,co,al合金相结构及电化学性能研究-study on phase structure and electrochemical properties of lam gni 3.6 m 0.4 m = ni, co, al alloy in rapid quenching state.docxVIP

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2018-05-29 发布于上海
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快淬态lamgni3.6m0.4m=ni,co,al合金相结构及电化学性能研究-study on phase structure and electrochemical properties of lam gni 3.6 m 0.4 m = ni, co, al alloy in rapid quenching state.docx

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快淬态lamgni3.6m0.4m=ni,co,al合金相结构及电化学性能研究-study on phase structure and electrochemical properties of lam gni 3.6 m 0.4 m = ni, co, al alloy in rapid quenching state

AbstractThe popularity of electric cars brings urgent demand for power batteries. With its large discharge current and high safety performance, Ni-MH battery has a broad space for development in the field of power battery. However, the actual discharge capacity of LaNi5 Ni-MH battery applied in commerce, is already very close to its theoretical capacity 348 mAh·g-1. Therefore, it is the key to the development of Ni-MH battery to exploit new negative electrode materials with high capacity for Ni-MH battery. Among negative electrode materials of Ni-MH batteries, the theoretical capacity of LaMgNi4 alloy is up to470 mAh?g-1,which will be negative electrode materials of Ni-MH battery, possiblyreplacing commercial AB5 hydrogen storage alloy in the near future.By replacing a small amount of Ni in LaMgNi4 with Co, Al, Cu and Mn, it finds that of LaMgNi3.6Co0.4 and LaMgNi3.6Al0.4 show better capacity. On the basis of previous researches, thin sheet samples were obtained at a cooling speed of 1, 3, 5 and 10 m/s using vacuum rapid quenching. Then XRD, SEM and EDS of the samples were analyzed. Results showed that multiphase structures were found in LaMgNi4, as well as LaMgNi3.6Co0.4 and LaMgNi3.6Al0.4. Same phase compositions were discovered in LaMgNi3.6Co0.4 and LaMgNi4 , that is LaNi5 and LaMgNi5. While, fewer amount of LaNi5 were observed in LaMgNi3.6Co0.4, and the content of LaNi5 phase was significantly reduced with the increasing of cooling speed. LaMgNi4 and LaAlNi4 were the main phase compositions of LaMgNi3.6Al0.4, without large changes with rotate speed increasing. SEM and EDS analysis indicated that lamellar structures were found in LaMgNi4 and LaMgNi3.6Co0.4. What’s more, LaNi5 was distributed in the center of crystalline grains, while LaMgNi4 distributed on the edges. Though lamellar structures were found in SEM spectrum of LaMgNi3.6Al0.4, no obvious two phrase structure was presented at a cooling speed of 1 m/s, while acicular crystal grains were found