金属氧化物催化生物质微米燃料燃烧特性的实验分析-experimental analysis of combustion characteristics of biomass micron fuel catalyzed by metal oxides.docx

铁钙比和生物质结渣特性指数推断，添加 2%wt 的金属化合物均加重了微米燃料的结渣程度。旋风燃烧对课题组已有的微米燃料旋风燃烧系统进行了调试，确定其最佳过氧 空气系数和进料量分别 1.26 和 360g/min。在此工况下进行了微米燃料与 2%wt 添加 剂混合样品的催化燃烧实验，对比添加添加剂前后的炉膛温度和烟气成分，得出以 下结论：在最佳工况下，微米燃料旋风燃烧最高温度为 1260℃；CaO 和白云石在 1000℃以下对微米燃料的升温速率和最高温度无明显影响，1000℃以上时，升温速 率加快，最高温度分别提高至 1280℃和 1275℃，MgO 则降低二者的值；烟气分析表 明，CaO 和白云石降低 CO 排放量，MgO 使其略微升高；MgO 可以降低烟气中 NOx 的排放量，CaO 和白云石则增加其排放。关键词：生物质微米燃料，金属氧化物，热重分析，静态混燃，旋风燃烧AbstractBiomass direct combustion is the most widely used, simplest and cheapest way among biomass utilization approaches. But its lower burning temperature and efficiency has long limited its application. Hence, Huazhong University of Science and Technology (HUST) developed biomass mocron fuel (BMF) high temperature combustion technology according to the dust explosion and high temperature combustion principle. Researchshows that, air combustion temperature of BMF can reach 1260℃, and oxygen-enrichedcombustion can go as high as 1600℃. But the former still can not meet the requirements of large-scale industrial application, the latter consumes large amounts of oxygen, resulting in higher cost. Therefore, Consider solid phase catalytic combustion of BMF, study the influences of catalytic additives on the ignition, burnout characteristics, averagereactivity, comprehensive combustion characteristics, combustion temperature, heating rate as well as exhaust gas emission feature of it , is a new and significant method to efficiently use BMF combustion technology.Alkaline metal oxides MgO, CaO and dolomite whose main components are Ca and Mg have been selected as additives to carry out the thermogravimetric analysis, static mix cumbustion and cyclone combustion experiment of BMF-additive mixtures.Thermogravimetric analysis analyzed the ignition, burnout, comprehensive combustion characteristics, average reaction activity and kinetics characteristics of BMF samples with 1%wt, 2%wt and 3%wt additives. Rresults show that, except samples with 3%wt MgO and 3%wt CaO, all the other samples with