金山石油焦催化气化反应特性分析-analysis of catalytic gasification reaction characteristics of jinshan petroleum coke.docx

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金山石油焦催化气化反应特性分析-analysis of catalytic gasification reaction characteristics of jinshan petroleum coke.docx

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金山石油焦催化气化反应特性分析-analysis of catalytic gasification reaction characteristics of jinshan petroleum coke

焦在不同温度下的气体释放规律同石油焦原样的释放规律一致，并且N2焦和H2O焦催化气化气体产物中各组分变化并不明显。关键词：石油焦催化气化气化反应性气体释放AbstractBecauseofanincreasingoutputofpetroleumcoke,howtoeffectivelyusepetroleumcokehasbecomeanurgentproblem.Withthesamechemicalcompositionofpetroleumcokeandcoal,itisapossiblewaytousepetroleumcokebygasification.Butthereactivityofpetroleumcokeislow,soitisimportanttochoosethesuitablegasificationcatalystwhichnotonlyimprovesthereactivityofpetroleumcoke,butalsocontrolsthecompositionofgasproducts.Inthispaper,wetookJinShanpetroleumcokeastheresearchobjectandaddeddifferentdosesofK2CO3inthepetroleumcokebyvolumetricimpregnationmethod.First,steamcatalyticgasificationofpetroleumcokewasperformedusingalaboratoryfix-bedreactorwithanonlinecoalgasanalyzer.Theexperimentalresultsshowthatcatalyticgasificationnotonlyeffectivelypromotesthegasificationreactivity,butalsocontributestohighH2andlittleCH4.ThereleasecharacteristicsofCO,H2,CO2andCH4aresimilarinthesamecondition.Thehighergasificationtemperature,thelargerpercentageofCOandthesmallerpercentageofCO2andH2.ThemoreadditiveamountofK2CO3,thesmallerpercentageofCOandthelargerpercentageofCO2andH2.TheyieldofCO2hasapositivecorrelationwiththepercentageofH2inthegasproducts.Thereisatemperaturerange,whichnotonlymakespetroleumcokehavehighergasificationreactivity,butalsohaveahigheryieldofH2.Second,theCO2catalyticgasificationofpetroleumcokewasperformedusingaTGA.Theexperimentalresultsshowthatbecauseofahighergasificationtemperature,thetimeatwhichthereactionwasfinishedwasshortenedandwiththemoreadditiveamountofK2CO3,thetimeisalsoshortened.Atthesametime,wehaveestablishedanormaldistributiondynamicsmodelofCO2catalyticgasificationofpetroleumcoke.Throughthecalculationresultswecanknow,thereactionactivationenergysignificantlyreducedafteraddingK2CO3.ThemoreadditiveamountofK2CO3,thelowerreactionactivationenergy.What’smore,theCO2catalyticgasificationofpetroleumcokehasobviouskineticcompensationeffect.Atlast,weuseFourier-transfclrillinfrared(FTIR)analyzerandSpecificsurfaceareaandporesizeanalyz