铑催化n-rhodium catalyzed n.docx

目录摘要................................................................................................................................IAbstract.........................................................................................................................II第一章前言..................................................................................................................11.1铑催化概述......................................................................................................11.2N-磺酰基-1,2,3-三氮唑简介11.3铑催化N-磺酰基-1,2,3-三氮唑的反应31.3.1含氮杂环化合物的合成.......................................................................31.3.2环丙烷化及相关反应........................................................................121.3.3芳基化及重排反应.............................................................................151.4本章小结.......................................................................................................20第二章铑催化三氮唑与水杨醛合成苯并[1,4]氧氮杂卓类化合物........................212.1苯并[1,4]氧氮杂卓类化合物概述...............................................................212.1.1苯并[1,4]氧氮杂卓类化合物的用途................................................212.1.2苯并[1,4]氧氮杂卓类化合物的合成方法及研究现状....................212.1.3课题的提出........................................................................................252.22,5-环氧苯并[1,4]氧氮杂卓化合物的合成..................................................272.2.1反应条件的优化................................................................................272.2.2反应底物的拓展研究........................................................................302.32,5-环氧苯并[1,4]氧氮杂卓化合物的衍生化研究......................................352.4反应机理的探究...........................................................................................362.5本章小节.......................................................................................................39第三章铑催化三氮唑合成异喹啉化合物的适用性研究........................................403.1异喹啉化合物概述.......................................................................................403.1.1