锂空气电池多孔碳电极材料的制备及性能分析-preparation and performance analysis of porous carbon electrode materials for lithium air battery.docx

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2018-05-29 发布于上海
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锂空气电池多孔碳电极材料的制备及性能分析-preparation and performance analysis of porous carbon electrode materials for lithium air battery.docx

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锂空气电池多孔碳电极材料的制备及性能分析-preparation and performance analysis of porous carbon electrode materials for lithium air battery

AbstractCrucialenvironmentalissuestogetherwithenergyresourcecrisismakethedevelopmentofimprovedlithiumbatteriesaworldwideimperative.Althoughlargecapacitylithium-ionbatteryforelectricvehicle(EV)hasattractedmuchattention,itsenergydensityisstilllimitedbythepositiveelectrode.Lithiumairbatteriesexhibitamuchhighertheoreticalspecificenergythananyotherenergystoragesystemsinthattheiractivecathodematerial,oxygen,doesnothavetobestoredinthebattery,butratheritcanbeaccessedfromtheenvironment.Lithiumairbatteryhasthehighesttheoreticalspecificenergyof11,140Whkg-1,excludingO2,whichprovidesenergydensityanorderofmagnitudelargerthanconventionalbatteriesandhasthepotentialtobecomeanewgenerationofsecondarybattery.But,thedischargeproductLi2O2andLi2Oarebothnotsolubleinorganicelectrolyteanddepositedinacarbon-basedporousairelectrodeonly.Therefore,thedesignofacarbonmatrixwithafavorablestructurewillbeanimportantsteptoimprovecellperformance.Meanwhile,theairelectrodeneedstoaddcatalysttoimprovetheO2reductionreaction.Inthispaper,thestudiesonpreparationandelectrochemicalperformancesofcatalystandporouscarbonselectrodematerialwereinvestigated.Aseriesofmanganesedioxideswerepreparedbyhydrothermal.Thepreparedα-MnO2nanordwithadiameterof100nmandalengthof2um,andtheβ-MnO2wasgranular.Theα-MnO2showsahighestinitialdiscapacityof1239.9mAhg-1anddischargeplateauof2.5Vatacurrentdensityof0.15mAcm-2.TheMOF-PCwasagraphitizedamorphouscabornandsynthetizedbyhydrothermal.Theas-preparedMOF-PCwithaspecificsurfaceareaof654m2g-1,porevolumeof0.76cm3g-1.TheMOF-PCcarbonblackairelectrodeshowsahighercapacityof1502.9mAhg-1atacurrentdensityof0.15mAcm-2,comparedtotraditionalSuperPcarbonblack.Andthecellretentionremainswiththedischargecapacityof287.6mAhg-1aftertencycles.hehighestdischargecapacnthecaseofdeepdischasofHPCs-3wasratherpIAseriesofhierarchicallyporouscarbonswerepreparedbynickelnitrateandsurfactant.Allcarbonsamplesweremainlymesoporousmaterialsandpossesssimilarporesizeandporesizedistribution.TheHPCs-3showsthelargestspecificsurface