钒酸钡基低介ltcc微波介质复相陶瓷的制备与性能分析-preparation and performance analysis of barium vanadate - based low-dielectric ltcc microwave dielectric multiphase ceramics.docxVIP

下载本文档

2
0
约8.16万字
约 70页
2018-05-29 发布于上海
举报
版权申诉

钒酸钡基低介ltcc微波介质复相陶瓷的制备与性能分析-preparation and performance analysis of barium vanadate - based low-dielectric ltcc microwave dielectric multiphase ceramics.docx

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

钒酸钡基低介ltcc微波介质复相陶瓷的制备与性能分析-preparation and performance analysis of barium vanadate - based low-dielectric ltcc microwave dielectric multiphase ceramics

Farbarction and Properties of Ba3(VO4)2-Based Low-Permittivity and Low-temperature fired Microwave Dielectric CompositeABSTRACTAs the key materials of microwave substrate, dielectric antenna and other microwave components, the low-permittivity LTCC microwave dielectric ceramics have been widely utilized in microwave communication systems. In this dissertation, the near-zero τf value materials were synthesized through combining the positive τf value material (Ba3(VO4)2) and negative τf value materials (Zn2-xSiO4-x and LiMg0.9Zn0.1PO4), to compose the Ba3(VO4)2-Zn2-xSiO4-x and Ba3(VO4)2-LiMg0.9Zn0.1PO4 composite ceramics with low-temperature cofireability. The relationships between the processing methods, phase compositions, microstructure and the microwave dielectric properties of the composite have been investigated by XRD, SEM, EDS, Raman Spectrum and network analyzer, etc. The main contents are listed as following:First of all, the XRD results indicated that the Zn1.87SiO3.87 powder without ZnO secondary phase was prepared by controlling the ZnO deficiency with the Zn/Si ratio of 1.87:1. The SEM studies demonstrated the coexistence of Ba3(VO4)2 and Zn1.87SiO3.87 phases in the (1-y)Ba3(VO4)2-yZn1.87SiO3.87 composite sintered bodies, as further confirmed by XRD and Raman results. A slight amount of silicon-rich secondary phases may increase the dielectric loss of the composite, as a result, the composite with 40% Zn1.87SiO3.87 sintered at 1100 oC exhibited desirablemicrowave dielectric properties of εr~9.3，Q×f~24000 GHz， and τf~-0.4 ppm/oC.Secondly, adding the B2O3 into the 0.5Ba3(VO4)2-0.5Zn1.87SiO3.87 composite ceramic can not only induce the formation of B2O3-SiO2 liquid phase where the B2O3 reacted with the armorphous SiO2 in the composite, but also may reduce the amount of the silicon-rich secondary phase. As a result, the sintering temperature and dielectric loss of the composite were significantly decreased. The 3 wt% B 2O3doped 0.5Ba3(VO4)2-0.5Zn1.87SiO