改性bamg13nb23o3透明陶瓷的制备与性能研究-preparation and properties of modified bamg 13 nb 23 o3 transparent ceramics.docxVIP

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改性bamg13nb23o3透明陶瓷的制备与性能研究-preparation and properties of modified bamg 13 nb 23 o3 transparent ceramics.docx

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改性bamg13nb23o3透明陶瓷的制备与性能研究-preparation and properties of modified bamg 13 nb 23 o3 transparent ceramics

(4) 研究了 Sm3+掺杂 Ba(Sn, Mg, Nb)O3 透明陶瓷的光致发光性能。通过测试不同 Sm3+掺杂量粉体的吸收光谱，发现 Sm3+掺杂量为 1 mol%的曲线上可以观察到 407 nm 和 468 nm 两处出现吸收峰。对 Sm3+掺杂 Ba(Sn, Mg, Nb)O3 透明陶瓷监控 407 nm 激发时，可观察到明显的黄光（562 nm）、橙光（597 nm）和红光（643 和 703 nm）；监控 597 nm 发射时，可分别观测到 346、363、379、407、 419、437、462、480、498 和 527 nm 处存在激发峰，其中 407 nm 为材料的有效激发峰，这些荧光峰均属于 Sm3+的 4f-4f 辐射跃迁。所以，Sm3+掺杂 Ba(Sn, Mg,Nb)O3 透明陶瓷具有用作近紫外 LED 激发的潜力。关键词：Ba(Mg1/3Nb2/3)O3 透明陶瓷，晶型结构，显微结构，光学性能，光致发光材料IIAbstractCompared to the glass and single crystal, transparent ceramics not only have high transparency and corrosion resistance, but also can work in extreme environment (high temperature and pressure). Transparent ceramics are gradually applied in various fields such as optical, lighting, high temperature and wireless electronic technology due to their high thermal conductivity, resistance against high strength and excellent dielectric properties. In this paper, M 4+ doped Ba(Mg1/3Nb2/3)O3 (M= Sn, Zr) transparent ceramics were synthesized by a solid state reaction. The influences of sintering techniques as well as the doping amount of M4+ ion on crystal structure, microstructure and optical properties were studied. The factors influencing the transmittance of transparent ceramics were analyzed and the correlation of microstructures and macroscopic properties was discussed as well. Moreover, the photoluminescence properties of Sm3+ doped Ba(Sn, Mg, Nb)O3 transparent ceramics were investigated.The influence of preparation process on crystal structure of Sn4+:Ba(Mg1/3Nb2/3)O3 transparent ceramics was analyzed by TG-DTA, XRD, particle size analysis and SEM. The results showed that when the additive amount of Sn4+ ion was above 10 mol%, the ceramics had cubic structure without birefringence. However, there appeared second crystalling phases when the additive amount of Sn4+ ion reached 15 mol%. Moreover, the densities of ceramics increased to a maximum, and then decreased with the increasing sintering ti