高电压4.35v锂离子正极材料lini0.5co0.2mn0.3o2的制备与改性研究-preparation and modification of lini 0.5 co 0.2 mn 0.3 o 2, a high voltage 4.35 v lithium ion cathode material.docxVIP

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高电压4.35v锂离子正极材料lini0.5co0.2mn0.3o2的制备与改性研究-preparation and modification of lini 0.5 co 0.2 mn 0.3 o 2, a high voltage 4.35 v lithium ion cathode material.docx

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高电压4.35v锂离子正极材料lini0.5co0.2mn0.3o2的制备与改性研究-preparation and modification of lini 0.5 co 0.2 mn 0.3 o 2, a high voltage 4.35 v lithium ion cathode material

4.35V, the results show that the first discharge was 170.2mAh/g, the discharge capacity after 100 times cycles was 159.5mAh/g. The cycling retention capacity after 248 times cycles was more than 80%.The 0.5%Al2O3 coated sample was tested at 25℃, 0.5C rate current between 2.75and 4.35V, the results show that the first discharge was 174.9mAh/g, the discharge capacity after 100 times cycles was 169.9mAh/g. The cycling retention capacity after256 times cycles was more than 80%, and the performance of ratio and high temperature storage is also good.Comprehensive modification experiment results,Al3+ doping can better improvethe cycle performance of ternary material, Ti4+ doping in the view of improving the performance of material circulation will not reduce the capacity at the same time, Al2O3 coating is good to prevent the corrosion of electrolyte to positive activematerial，stabile material structure.Keywords:coprecipitation;LiNi0.5Co0.2Mn0.3O2;highvoltage;cycle performance;III目录摘要.................................................................................................................................IAbstract ..........................................................................................................................II第一章绪论................................................................................................................11.1锂离子电池发展历程....................................................................................11.2锂离子电池工作原理....................................................................................11.3锂离子电池性能特点....................................................................................21.4锂离子电池正极材料的发展现状................................................................31.4.1一元锂离子正极材料..........................................................................31.4.2二元锂离子正极材料..........................................................................51.4.3磷酸铁锂系正极材料..................................................