新型高性能电纺tpupvdf凝胶聚合物电解质制备与研究-preparation and study of novel high performance electrospinning tpu pvdf gel polymer electrolyte.docxVIP

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新型高性能电纺tpupvdf凝胶聚合物电解质制备与研究-preparation and study of novel high performance electrospinning tpu pvdf gel polymer electrolyte.docx

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新型高性能电纺tpupvdf凝胶聚合物电解质制备与研究-preparation and study of novel high performance electrospinning tpu pvdf gel polymer electrolyte

AbstractPolymer electrolyte is the important part of lithium-ion batteries and it plays a vital role in the performance for lithium-ion battery. In recent years, gel polymer electrolyte aroused general interest. This paper aims to prepare a novel kind gel polymer electrolyte by electrospinning technique which has high ionic conductivity and excellent mechanical properties. Study the physical and chemical properties of gel polymer electrolytes, and investigate the cycle performances and the rate capabilities of gel polymer electrolyte in lithium ion polymer battery. The main contents of this dissertation are as follows:Firstly, we chose thermoplastic polyurethane (TPU) and poly (vinylidene fluoride) (PVDF) as matrixs for gel polymer electrolytes (GPEs). Then a novel blend-based gel polymer electrolyte (GPE) films have been prepared with electrospinning. The TPU/PVDF electrospun membranes are activated with a 1M solution of LiClO4 inEC/PC and show a high ionic conductivity about 1.6 ×10-3 S·cm-1 at room temperature.The electrochemical stability is at 5.0V versus Li+/Li. Cycling performances of Li/GPE/LiFePO4 cells are also performed well to test the suitability of the electrospun membranes.Secondly, nonwoven films of composites of TPU with different proportion of PVDF are prepared by electrospinning 9wt% polymer solution at room temperature. Then GPEs are prepared by soaking the electrospun TPU/PVDF blending membranes in 1M LiClO4/ethylene carbonate (EC) /propylene carbonate (PC) for 1 h. The gelpolymer electrolyte (GPE) shows a maximum ionic conductivity of 3.2×10-3 S·cm-1 atroom temperature and electrochemical stability up to 5.0V versus Li+/Li for the 1:1 blend ratio of TPU:PVDF system. At the first cycle, it shows a first charge–discharge capacity of 168.9 mAh·g-1 when the gel polymer electrolyte (GPE) is evaluated in a Li/PE/lithium iron phosphate (LiFePO4) cell at 0.1 C-rate at 25 oC. TPU/PVDF (1:1, w/w) based gel polymer electrolyte is observed much m