新型酞菁类光伏材料的合成及性能分析-synthesis and performance analysis of novel phthalocyanine photovoltaic materials.docxVIP

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新型酞菁类光伏材料的合成及性能分析-synthesis and performance analysis of novel phthalocyanine photovoltaic materials.docx

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新型酞菁类光伏材料的合成及性能分析-synthesis and performance analysis of novel phthalocyanine photovoltaic materials

AbstractSolarenergyisoneofthelargestandabundantrenewablesourcesofenergyinthisplanet.Butonlyasmallpartofitwasusedmainlyduetothelackofeffectiveapproachtoharvestit.Amongtheapproachesproposedtoharvestsolarenergy,polymerbulkhetero-junctionsoalrcells(BHJ)anddye-sensitizedsolarcells(DSSCs)havebecomearesearchhotspotduetotheirlowcost,easytomanufacturingandhighefficiency.Phthalocyanines(Pcs),similartoporphyrins,beingoflargeringmoleculeshave18πelectronsandpossessastrongabsorptionbandinthered/near-infraredregion.Therefore,Pcsareverysuitabletoapplicateinthefieldofphotovoltaiccells.ThemainpointsthattheresearchonphthalocyaninederivativesaretotobroadenitsnarrowSoret-band,andsimultaneouslyimprovethepoorsolubilityandamelioratetheweaknessofeasyaccumulation,expectingofobtainingmaterialsthatcouldusedinsolarcellsandreachinghighefficiency.Inthisthesis,onthebasisofphthalocyanineasthemaindirection,wedesignedandsynthesizedtwophthalocyanineend-cappedcopolymersandorganicdyesbasedonphthalocyaninethatwasmodifiedwiththienylorphenylgroups.Allofwhichwereappliedinsoalrcells.Thestructuresoftheintermediateproductsandthetargetproductswereanalysisedusingavarietyofmethods.Andthephotophysical,electrochemicalnaturesofthecopolymersandphthalocyaninedyeshavealsobeendiscussedthorough.Thephotovoltaicperformanceofthesolarcellscorrespondingtothetwocopolymersend-cappedwithphthalocyaninesandphthalocyaninedyeswerealsoanalysisedanddiscussed.Theresultsareasfollows:WesynthesizedtwocopolymersPHY1andPHY2,end-cappedbyphthalocyanie,containingthiophenesandbenzothiadiazole(BTZ)moietiesinthesidechainforbulkhetero-junctionsolarcells.Multiplephysicchemicalpropertiesofthetwocopolymers,includingthermalstabilities,photophysics,electrochemical,andphotoelectricperformance,wereinvestigated.TheresultselucidatethattheintroductionofphthalocyaninemoietyintheendingsofthepolymerscouldbroadenandstrengthentheabsorptionintheSoret-bandandQ-band.Wefabricatedthebulkhetero-junctionsolarcellsbasedonthecopolymersblendingwithPC61BMindiffirentweightr