以氮杂环羧(磺)酸为配体的配合物的合成及光电性能研究-synthesis and photoelectric properties of complexes with nitrogen heterocyclic carboxylic acid as ligand.docx

以氮杂环/羧(磺)酸为配体的配合物的合成及光/电性能研究中文摘要关键词：配合物，光稳定，荧光，电存储作者：陈洪霞指导教师：路建美、徐庆锋英文摘要以氮杂环/羧(磺)酸为配体的配合物的合成及光/电性能研究SynthesisandStudytheOpticalandElectricalPropertiesoftheN-containingHeterocyclic,Carboxylic(Sulfonic)LigandsandTheirMetalCompoundsAbstractInrecentyears,coordinationcompoundshaveattractedconsiderableattentionduetotheirintriguingstructuraltopologiesandpotentialstobeemployedasfunctionalmaterialsinfluorescence,catalysis,adsorption,nonlinearopticsandmagnetism.Thedesignandconstructionofmulti-dimensional,multi-nuclearcoordinationcompoundsviaassemblyreactionsofmetalionswithfunctionalligandsisoneofthehottestresearchtopics.Organicligandsareimportantelementswhenconstructingthecoordinationcompounds.Functionalligandsnotonlyaffectthesynthesisofcoordinationcompounds,butalsotheirstructures,stabilityandperformances.Inthisdissertation,wechosethe4-(8-hydroxyquinoline-5-azo)-benzensulfonicacid(H2QBS),2-(1H-imidazol-1-yl)aceticacid(Hima),o-methacrylamidobenzoicacid(o-MAABA)toreactwith4,4’-bpy,1,10-Phenandmetalions.Finally,aseriesofcoordinationcompoundsandcoordinationpolymerswereobtained.Basedonthestructuralcharacterizationsofthecorrespondingcompounds,theirchemicalandphysicalproperties,suchasphotoluminescenceandUV-visspectrawereinvestigated.Moreover,compoundswithgoodsolubilitywereselectedandmemorydevicesbasedonthesecompoundswerefabricatedtostudytheirmemoryeffects.Theseresultswerebrieflydescribedasfollows:ThereactionbetweenmetalsaltsandH2QBSgaverisetofivecoordinationpolymers:[Na2(QBS)(H2O)2]n(1,3Dframework),{[Pb(QBS)(DMSO)]·2(iPrOH)}n(2·2iPrOH,2Dlayer),{[Zn(QBS)(DMSO)]·2DMSO}n(3·2DMSO,1Dchain),[Mn(QBS)(iPrOH)(DMSO)]n(4,1Dladder)and[Cd2(QBS)2(DMSO)2(H2O)4]n(5,1Dchain).ThesecoordinationpolymerswerecharacterizedbyelementalanalysisandIRspectroscopyandX-raydiffraction.Theirphoto-stabilitywasalsostudiedbyirradiationofdifferentlightsources(450nm,365nmand254nm).Underbluelight(450nm)and365以氮杂环/羧(磺)酸为配体的配合物的合成及光/电性能研究英文摘要nmlight,thecolorsofallcompoundswerewellpreservedandabsorptionspectrashowedslightl