印钞擦版浓缩废水处理的分析-analysis of concentrated waste water treatment for banknote printing and erasing plate.docxVIP

摘要印钞擦版浓缩废水是印钞生产中最主要的生产废水，这种废水排放量大，含有大量的碱、油墨、表面活性剂和有机物等污染物，废水的浓度高、色度大、含盐量较高、碱性偏大、可生化性能差，具有高乳化性和强亲水性等特点，其处理难度大，成本及运行费用较高。若不经处理任意排放对环境和水体会造成严重的危害。本研究通过物理、化学和生化相结合的方法针对印钞废水进行处理，使出水COD≤150mg/L，达到了企业排放水要求。并通过各项试验对处理工艺运行参数进行优化，为印钞擦版浓缩废水处理的工程设计和调试运行提供理论依据。本研究对印钞擦版废水进行超滤，然后利用二氧化碳对超滤后的浓缩液进行破乳，并确定了二氧化碳破乳法的工艺条件。经破乳后的污水经水解酸化、生物接触氧化、生物碳和两级生物接触氧化等工艺试验测试。根据试验数据分析，深度水解酸化和生物接触氧化的工艺去除率最大。研究表明，水解酸化和生物接触氧化组合工艺对擦版废水破乳后清液废水进行处理，当环境温度保持在14℃以上，总水力停留时间6d，进水化学需氧量（ChemicalOxygenDemand，COD）为2000mg/L，出水CODCr为140mg/L，去除效率大幅度提高到94%。另外，超滤后的擦版浓缩废水采用CO2/CaCl2法破乳比CO2/PAM法效果更稳定。深度水解酸化和生物接触氧化工艺小型试验和中型试验数据结果基本一致，达到预期的要求，本工艺经论证已做为印钞公司新建综合污水处理站工艺。关键字：擦版浓缩废水水解酸化生物接触氧化二氧化碳破乳法去除率IAbstractThemainkindofwastewaterproducedduringtheproductionofbanknoteprintingistheconcentratedwastewaterfromwipingforme,whichhasalargeamountofemission.Itcontainsquantitiesofpollutantssuchasalkali,ink,surfaceactiveagent,organicmatterandsoon,andwiththecharacteristicsofhighconcentration,darkcolority,highsalinity,strongalkalinity,poorbiodegradibility,highemulsifyingabilityandstronghydrophilicity.Itishardtotreatthewastewater,thecostandoperatingexpenseisalsoexpensive,andthedischargedwastewaterwilldoharmtotheenvironmentandwatersifitisnottreatedwell.Thisstudyindicatesthat,thevalueoftheeffulentchemicaloxygendemand,COD,couldbenomorethan150mg/Lafterwastewatertreatmentthroughthecombinedmethodofphysical,chemicalandbiochemical,thusmeetstherequirementsofdischargedwaterinenterprises.Furthermore,theprocessparametershavebeenoptimizedthroughdifferenttests,whichprovidesatheoreticalbasisfortheengineeringdesignandcommissioningoftheconcentratedwastewipingsolutiontreatment.Inthisstudy,testsweremadefirstlytoultrafilterthewastewipingsolution,thendemulsifyitwithCarbondioxide,andfinallydeterminetheprocessconditionsofCarbondioxidedemulsification.Thedimulsifiedwastewaterwillbetreatedwithseveralprocesstests,includinghydrolyticacidification,biologicalcontactoxidation,biologicalcarbonandtwo-stagebiologicalcontactoxidation,etc.Basedontheteststatistics,itsuggeststhatth