一种可湿气自修复涂层聚合物的分解与表征.pdf

摘要 摘要 本论文以异佛尔酮二异氰酸酯(IPDI)、二缩三乙二醇(TEG)和甲基丙烯 酸羟乙酯(HEMA)为原料制备了含异氰酸酯端基的丙烯酸酯单体ITEGMA， 再将该单体与甲基丙烯酸六氟丁酯(HFBMA)以不同比例共聚，得到了不同组 成比的含有异氰酸酯活性基团的，又含有疏水氟单元的共聚物poly 过的铝片上成膜后，发现该膜在湿气条件下具有自修复的性质，并且膜的自修 复性能取决于单体ITEGMA与HFBMA的共聚组成。研究结果表明，共聚组成 酯的ITEGMA主要影响膜的修复能力；而与之相对应，含有疏水氟单元的 HFBMA主要影响膜的表面性能和并对膜内部的异氰酸酯基团起保护作用。当涂 膜遭受破坏，裂纹两边的异氰酸酯基团能与环境中的水分发生反应形成脲键并 且通过“拉链”机理修复裂纹。 关键词：自修复聚异氰酸酯一含氟丙烯酸酯 拉链机理 Abstract An monomerITEGMAwas from ． isocyanatecontainingmetharcylate prepared diisocyanate(IPDI)，triethyleneglycol(TEG)and isophorone 2-hydroxyethyl then with copolymerized methacrylate(HEMA)，and form radical methacrylate(HFBMA)to by coated onaluminum polymerization．After sheet，the filmexhibitedaself andwhichWas to copolymercoating healingperformance related the ofITEGMAtoHFBMA．Asthe composition healing mflueIlcedthe asthe mainly repairingperformance,whileprotectioncomponent HFBMAcontributedtothesurface ofthe and the mainly propertycoatingprotected ITEGMAinsideofthe from totheenvironmentcondition． part coatingexposing Oncethe from on1TEGMACallreact coatingsufferingdamage，isocyanategroups with toformaureacrosslinkandcrackswereselfhealed the H20 rapidly through model”mechanism．Themoistureactiveself behaviorofthe ‘zipper