干胶转化法研讨沸石转晶和沸石表面修饰.pdfVIP

度远远大于补硅 的速度 ，从而产生介孔 ，达不到缩小沸石表面孔径 的作用 ；通过 调 节氟硅 酸铵 的浓度 （0.11 M ) , 油浴温度 （80 °C ) 并加入醋酸铵缓冲溶液调节 溶液pH 值在 6~7 之间，使补硅的速度无限接近于骨架脱铝的速度，从而达到缩 小沸石表面孔径 的 目的，将得 到 的表面孔径 收缩程度不 同的 Z SM -5 沸石 ，应用 于 室温 下 分离三 种 二 甲苯 的混 合物 。 关键词 ：沸石转 晶，干胶转化法 、Y 沸石 ，U SY 沸石 ，*B EA 沸石 ，空心结构 ， 局 部有序 ，孔径 缩 小 A b str a c t In general, zeo lite is synthesized under hydrotherm al condition u sing an am orphou s alum ino silicate gel as a starting m aterial. H ow ever, som etim es it is ob served that the form ation of a zeo lite phase m ay be preceded w ith another phase during the course of zeo lite cry stallization . T h is phenom enon, therefore, cou ld be con sidered to be an alternative synthesis strategy for the hydrotherm al conversion of on e zeo lite into anoth er，i.e., zeo lite—zeo lite tran sform ation . In fact, th is m ethod is of attractive research area, since it m ay provide inform ation about the crystallization m echan ism and a lso is an outstand ing route to obtain a n ew zeo lite w h ich cannot b e cry stallized by a con ventiona l m ethod . F irstly, steam -assist crystallization m ethod w as introduced to study zeo lite-zeo lite transform ation. H C l-treated Y zeo lite w as u sed as precursor, study ing the transform ation ru les in certain base and tem perature and also study ing th e conversion products in d ifferent tem peratures. T he resu lts w ere as fo llow ed :T he acid-treated Y zeo lites w ere alm ost am orph ou s but som e short-range-order alum inosilicate species w ere retained. T he acid-treated Y zeo lites w ere recrystallized at 150 °C w ith 0.3 m ol/L N aO H so lution by steam -assist cry stallization m ethod, and pure m orden ite zeo lite products w ith the m orp ho logy from aggregate of nano-rod to m icron-sized crystal w ere obtained w ith in su itab le S i/A l ratio range (3.95- 9.75) ;W h ile w ith S i/A l ratio below 3.95,