一个中心对称的拓扑二维蜂窝网的ni-咪唑基三脚架配合物的合成.docVIP

一个中心对称的(6, 3)拓扑二维蜂窝网的Ni-咪唑基三脚架配合物的合成、结构及其介电性 于银梅, 谭育慧(, 黄海平, 熊剑波, 王艳, 高继兴, 徐庆, 唐云志 (江西理工大学冶金与化学工程学院, 江西 赣州 341000) 摘 要: 本文利用水热合成法, 以金属盐NiSO4·6H2O与三脚架配体1, 3, 5-三(1-咪唑基)苯(tib)进行组装, 得到了一个结构新颖的有序金属-有机框架(MOFs) {[Ni3(tib)2(H2O)12](SO4)3}n (1)。利用X-射线单晶衍射仪检测其晶体结构, 并进行元素分析, 红外光谱射线, 粉末衍射等相关表征。配合物1为一个典型的(6, 3)拓扑二维蜂窝网结构, 由于π-π空间叠加效应和氢键相互作用形成了稳定的三维结构。对配合物1介电性能进行测定, 发现其在138℃时达到最大的介电异常值10.08, 为典型的介电材料, 通过热重分析, 表明此材料具有较好的热力学稳定性, 对新型多维MOFs及新型介电性能材料的开发具有借鉴和指导意义。 关键词: 水热合成; 晶体结构; 三角架配体; 拓扑 中图分类号: O731 文献标识码: A Synthesis, Crystal Structures, Dielectric Properties of one centric (6, 3) Topological 2-D Frameworks with Ni-Imidazole-containing Tripodal ligand YU Yin-Mei, TAN Yu-Hui*, HUANG Hai-Ping, XION Jian-Bo, WANG Yan, GAO Ji-Xing, XU Qing, TANG Yun-Zhi (School of Materials and Chemical Engineering Jiangxi university of Science and Technology, Ganzhou 341000, China) Abstract: The new novel metal-organic framework (MOFs) {[Ni3(tib)2(H2O)12](SO4)3}n (1) was obtained by hydrothermal reaction of the metal salt NiSO4·6H2O and the three-connecting ligand 1, 3, 5-tris(1-imidazolyl) benzene (tib). The crystal data and structure were established by single-crystal X-ray diffraction analysis, and characterized by elemental, IR, XRD, et al. Using SHELXL-97 software for the structure elucidation and Topos40 software for its topology analysis, shows that complex 1 is a 2D network honeycomb networks with (6, 3) topology, which was further linked together to three-dimensional (3D) frameworks by the spatial additive effect of π-π and interaction of hydrogen bonds. Dielectric constant studies show that complex 1 exhibits the (max reaches a value of about 10.08 in 138℃, which is the typical dielectric material. This material has good thermal stability indicated by thermogravimetric, providing a reference and guidance for the development of the novel multidimensional MOFS and dielectric properties of new materials. Key words: Hydrothermal reaction; Crystal Structure; Tripodal liga