腐殖酸对土壤铅赋存形态的影响（Effect of humic acid on the occurrence of lead in soil）.docVIP

腐殖酸对土壤铅赋存形态的影响（Effect of humic acid on the occurrence of lead in soil） Effect of humic acid on the occurrence of lead in soil The high jump 1, Han Xiaokai 1, Li Yanhui 2, guanlianzhu 1, Yan Li 1* 1. 、 School of land and environment, Shenyang Agricultural Uinversity, Liaoning, Shenyang; 110161; 2.. Shenyang agricultural testing center, Liaoning, Shenyang 110034 Abstract: through indoor cultivation experiments, the effects of different amounts of humic acid on Pb speciation in lead contaminated soil were investigated. The results showed that humic acid treatments could significantly reduce the exchangeable Pb in soil (EX-) (Cob-), carbonate bound and Fe Mn oxides (FeMn-) and the content of organic bound Pb (Ob-) and residual fraction (Res-) significantly increased the content of lead. Humic acid effectively reduced the activity of lead, and the influence degree increased significantly with the increase of humic acid dosage. Effect of humic acid on lead ions in soils of various forms of content change with time for 0~40 in culture during the period of D, with the prolongation of the culture time exchange without significant changes in Pb content, lead content of residue decreased significantly, the other three were increased; after 40 d culture, with culture time extend the various forms of content did not change significantly. It is considered that the humic acid with 10% mass ratio can significantly reduce the activity of lead, so as to achieve a better repair effect. Keywords: humic acid; soil; lead; speciation CLC number: X131.3 document identification code: A article number: 1672-2175 (2008) 03-1053-05 Table 1 Physical and chemical properties of tested soil Table 1 Basic physical and chemical properties in test soil Soil type texture w (organic matter) / (G. Kg-1) pH (H2O) w (CaCO3) / (G. Kg-1) B (CEC) / (CMoL. Kg-1) w (free iron oxide) / (G. Kg-1) w (amorphous iron oxide) / (mg. Kg-1) brown soil loamy 15.6, 6.5, 14.5, 16.3, 14.96, 84.62 Lead is a heavy metal with