负载型钯_金催化剂催化合成醋酸乙烯酯.docVIP

------------------------------------------------------------------------------------------------ —————————————————————————————————————— 负载型钯_金催化剂催化合成醋酸乙烯酯 石油化工PETROCHEMICAL TECHNOLOGY2016 年第45 卷第 11 期 DOI：10.3969/j.issn.1000-8144.2016.11.005? 负载型钯-金催化剂催化合成醋酸乙烯酯 胡华林1，2，莫羡忠1 （1.广西师范学院 化学与材料科学学院，广西 南宁 530001； 2. 贵州省中国科学院 天然产物化学重点实验室，贵州 贵阳 550002） ［摘要］ 采用等体积浸渍法制备了由硫代氨基脲硫醇化改性活性炭负载的钯-金催化剂，将该催化剂用于乙烯气相氧化法合 成醋酸乙烯酯（VA）的反应，利用AAS和XPS分析手段对催化剂的组成进行表征，并考察了不同钯/金质量比的催化剂 用于乙烯气相氧化法合成VA的催化活性。实验结果表明，当催化剂中钯/金质量比为1.11时，钯和金元素的负载率最大， 分别为89.40%和105.60%，该催化剂在乙烯气 相氧化法合成VA的时空收率和选择性达最佳值，分别为825.0 g/（L?h）和 95.1%。表征结果显示，活性组分钯、金在催化剂上的化学形态主要是由钯的氮化物或氧化物和金单质组成。 ［关键词］ 钯-金催化剂；醋酸乙烯酯；浸渍法；活性炭；硫醇化改性 ［文章编号］ 1000-8144（2016）11-1322-04 ［中图分类号］ TQ 426 ［文献标志码］ A Synthesis of vinyl acetate over supported palladium-gold catalysts Hu Hualin1，2，Mo Xianzhong1 （1. College of chemistry and Materials Science，Guangxi Teachers Education University， Nanning Guangxi 530001，China；2. The Key Laboratory of Chemistry for Natural Products of Guizhou Province，Chinese Academy of Sciences，Guiyang Guizhou 550002，China） ［Abstract］ Palladium-gold/thiolation modified activated carbon catalysts were prepared by impregnation and used in the synthesis of vinyl acetate(VA) by the vapor phase oxidation of ethylene. The catalysts were characterized by means of AAS and XPS. The effects of the Pd/Au mass ratio in the catalysts on their catalytic activities in the synthesis of VA were investigated. The expe rimental resu lts showed that，when the Pd/Au mass ratio was 1.11，both the Pd and Au loadings were the largest， up to 89.40% and 105.60% respectively，and both the space-time yield and the selectivity to VA in the synthesis reached the optimum，825.0 g/(L?h) and 95.1% respectively. The characterization results indicated that，Pd and Au in the catalysts existed mainly in the form of palladium nitrides or oxides and elementary substance