固相萃取-高效液相色谱-质谱联用法检测环境水样中种持久性有机污染物.docVIP

——————————————————————————————————————————————— 固相萃取-高效液相色谱-质谱联用法检测环境水样中5种持久性有机污染物 固相萃取-高效液相色谱-质谱联用法检测环境水样中5种持久 性有机污染物 罗黄世 覃国飞 王献 摘要：目的 定量检测环境水样中全氟辛酸（PFOA）、全氟辛磺酰酸（PFOS）、全氟己酸（PFHA）、双酚A（BPA）、3-羟基-四溴联苯醚（3-OH-BDE-47）5种持久性有机污染物。方法 采用固相萃取（SPE）和高效液相色谱-质谱联用分析方法（HPLC-MS）同时检测环境水样中5种持久性有机污染物。结果 该方法在1—1000 ng·mL-1的范围内具有良好的线性关系，检测限为1—8 ng·L-1，水样加标回收率为93.2%—110.1%，相对标准偏差（RSD）为2.7—9.1%。结论 该方法适用于复杂环境基质中微量或痕量环境污染物的检测，可以满足复杂水样中相关POPs的分析检测。 关键词：固相萃取，液相色谱-质谱联用，环境水样，全氟辛酸，全氟辛磺酰酸，全氟己酸，双酚A，3-羟基-四溴联苯醚 Detection of five persistent organic pollutants in environmental water samples using solid-phase extraction and high performance liquid chromatography- mass spectrometry LUO Huangshi，QIN Guofei，WANG Xian Abstract：Objectives To develope an analytical method for the detection of 5 persistent organic pollutants (POPs), namely, perfluorooctanoic acid (PFOA), perfluorooctane sulfonic acid (PFOS), perfluorohexanoic (PFHA), bisphenol A (BPA), 3-hydroxy polybrominateddiphenyl ether (3-OH-BDE-47). Methods Solid-phase extraction (SPE) and high performance liquid chromatography-mass spectrometry (HPLC-MS) were used for the determination of 5 persistent organic pollutants. Results The results showed good linear relationship in the dynamic range of 1—1000 ng·mL-1. The limits of detection (LODs) for the five compounds were 1—8 ng·mL-1. Recoveries of real water samples were obtained from 93.2%—110.1% and the relative standard deviations (RSD) were in the range of 2.7—9.1%. Conclusions This developed method can satisfy the detection of these POPs in water samples with complex matrices. Key words: solid-phase extraction (SPE), high performance liquid chromatography-mass spectrometry (HPLC-MS), environmental water sample, perfluorooctanoic acid (PFOA), perfluorooctane sulfonic acid (PFOS), perfluorohexanoic (PFHA), bisphenol A (BPA), 3-hydroxy polybrominateddiphenyl ether (3-OH-BDE-47) 全氟化合物广泛应用于厨具、纺织、包装、皮革和灭火泡沫等工业领域[1]，大量研究表明在粉尘、空气、土壤等环境介质中均能检测到全氟类化合物