气相法合成N-乙基苯胺催化剂及工艺条件的研讨.pdf

摘 要 本文对苯胺与工业乙醇气相法合成N一乙基苯胺的催化剂进行了筛选，找出了 活性最好的催化剂一1184催化剂。确定了反应的最佳工艺条件，在此条件下，对 该催化剂进行了稳定性考察。对产品进行了精馏实验。并用NH。一TPD法测定了催 化剂的表面酸性，对催化剂的表面活性和酸性进行了关联，确定了苯胺的N一乙基 化是在比较弱的L酸上进行的。同时还用BET法测定了催化剂的孔容和比表面积。 关键词：苯胺乙醇N一乙基苯胺催化剂 英文摘要 of andTechnicalConditions Research Catalysts of ofAniline Vapor—phaseN—ethylation Major：PhysicalChemistry Author：MaZhan Ling Tao Supervisot：ProfessorKeyi Inthis of in paper，severalcatalysts producingN-ethylaniline were industrialalcoholas vapor—phasestudied，by using alkylating technicalconditionsofthereaction in锄 agent．The weredetermined reactor．The ofthe was integral stability also catalyst such the and conditions，weenlarged achievedresults． experiment good Surface of acidic the were means properties characterized catalysts by of wasrelatedtothe surface catalytic acidity．It NH3一TPD．The activity was thatthereaction