自混合熔盐燃烧合成LiMn2O4初步研究.docVIP

自混合熔盐燃烧合成LiMn2O4初步研究 　　摘要:以低熔点醋酸锂（70-℃）和醋酸锰（80-℃）为原料，在不添加任何燃料的条件下，用熔盐燃烧合成法制备尖晶石型LiMn2O4正极材料.研究了600-℃点燃温度下，不同保温时间以及2次焙烧的工艺条件对产物的影响.结果表明，在600-℃通过延长保温时间不能得到单相尖晶石型LiMn2O4产物，只能得到主晶相为尖晶石型LiMn2O4的产物.保温时间1-h时产物中有Mn?3O4和Mn2O?3 2种杂质，而保温时间达3-h及以上时，产物中只有Mn2O?3杂质，其中以保温时间6-h得到的LiMn2O4含量最高，杂质最少；产物经600-℃ 2次焙烧12-h后可得到单相尖晶石型LiMn2O4物质，且增加焙烧时间大于12-h后对样品中成分基本无影响；产物中LiMn2O4的结晶性随焙烧时间增加而逐渐增加. 　　关键词:熔盐燃烧合成；尖晶石型LiMn2O4；醋酸盐；正极材料 　　中图分类号:O611；TM911 　　 文献标识码:A文章编号:1672-8513(2010)01-0036-03 　　A Preliminary Study of the Eutectic Self-Mixing 　　Molten-Salt Combustion Synthesis of LiMn2O4 　　GUO Jun?ming1，LIU Gui?yang2，BAI Xiao?hong2，WANG Zheng?liang1 　　（1. School of Chemistry and Biotechnology，Yunnan University of Nationalities，Kunming 650031, China；2.School of Science，Honghe University，Mengzi 661100, China） 　　Abstract: 　　Spinel LiMn2O4 for the cathode material of lithium ion batteries was prepared by molten-salt combustion synthesis, using eutectic point materials lithium acetate (70-℃) and manganese acetate (80-℃) as starting materials without any fuels. The effect of calcining time and second calcination at 600-℃ on the products was studied. The results indicated that single phase LiMn2O4 could not be synthesized through extension of calcining time at ?600-℃, but the product with the main phase of LiMn2O4 could be synthesized. There were two impurities Mn?3O4 and Mn2O?3 in the product calcined at 600 ℃ for 1 h. There was only one impurity Mn2O?3 in the product calcined at 600 ℃ for more than 3h, and the product with the highest content of LiMn2O4 and the lowest content of impurity was obtained at 600 ℃ for 6 h. Single phase LiMn2O4 was obtained after second calcination at 600 ℃ for 12 h, and the composition of products calcined more than 12 h changed little. The crystallinity of LiMn2O4 increased with the increasing calcining time. 　　Key words: 　　molten-salt combustion synthesis; spinel LiMn2O4; acetate; cathode material 　　 尖晶石型LiMn2O4正极材料锰来源丰富、成本低、无毒等优点，被认为是很有希望代替LiCoO2作为锂离子电池的正极材料