11-钨镉三元杂多阴离子层状化合物的合成、表征催化活性 毕业论文.doc

齐 齐 哈 尔 大 学 毕业设计（论文） 题　　目院 （系）　 化学与化学工程学院 专业班级　 化学0班 学生姓名　 指导教师　 成　　绩 20年 6月1日  摘 要 本文采用直接合成的方法合成了具有Keggin结构的11-钨镉三元杂多酸盐，分别为K8[NiCd(H2O)W11O39]K8[CuCd(H2O)W11O39]、K8[ZnCd(H2O)W11O39]、K8[Cd(H2O)W11O39]、K8[Cd(H2O)W11O39]、K8[Cd(H2O)W11O39]，并用离子交换法将已合成的11-钨镉三元杂多酸盐嵌入到Zn2Al类水滑石中，得到杂多阴离子层状化合物：Zn2Al-K8[ MCd(H2O)W11O39 ] (M = Ni2+、Cu2+、Fe2+、Zn2+、Co2+ 、Mn2+)，记作 LDH- K8[ MCd(H2O)W11O39 ]（M=Ni2+、Cu2+、Fe2+、Zn2+、Co2+、Mn2+），并用IR、UV、TG-DSC对杂多酸盐进行表征，用IR、X射线粉末衍射、TG-DSC对杂多阴离子层状化合物进行表征。结果表明，三元杂多阴离子嵌入到水滑石层间后，仍然保留了其Keggin结构。利用已合成的杂多阴离子层状化合物来催化合成乙酸正丁酯，得出最佳的催化条件，并考察几种杂多阴离子层状化合物的催化活性，实验结果表明，杂多阴离子层状化合物在酯化反应时有良好的催化活性。 关键词：三元杂多阴离子；层状化合物；Keggin 结构；酯化反应 Abstract In this paper, the direct synthesis method of synthesis of a Keggin structure 11 - tungsten cadmium ternary heteropoly salt，Respectively，they are K8[NiCd(H2O)W11O39]K8[CuCd(H2O)W11O39]、K8[ZnCd(H2O)W11O39]、K8[FeCd(H2O)W11O39]、K8[CoCd(H2O)W11O39]、K8[Cd(H2O)W11O39]And using the ion-exchange method to the synthesis of 11 - tungsten-cadmium ternary heteropoly salt respectively embedded in the Zn2Al Hydrotalcite, layered compounds of the heteropolyanion，get Heteropoly anionic layered compounds, they are Zn2Al-K8[ MCd( H2O)W11O39 ] (M = Ni2+、Cu2+、Fe2+、Zn2+、Co2+ 、Mn2+)，marked LDH- K8[ MCd( H2O)W11O39 ]（M=Ni2+、Cu2+、Fe2+、Zn2+、Co2+、Mn2+），ternary heteropoly salts were characterized by IR, UV and TG-DSC，and layered compounds of the heteropolyanion were characterized by IR, X, X-ray powder diffraction and TG-DSC。The results showed that ternary heteropolyanion embedded in the hydrotalcite interlayer, still retains its Keggin structure。The synthesis of the heteropolyanion layered compounds to catalyze the synthesis of butyl acetate, come to the best catalytic conditions, and studied the catalytic activity of several heteropolyanion layered compounds, layered compounds of the experimental results show that the heteropolyanionexcellent catalytic activity in the esterification reaction。 Key words: Ternary Heteropo