A Sensitive Electrochemical Sensor灵敏电化学传染器.pdfVIP

Electronic Supplementary Material (ESI) for RSC Advances. This journal is © The Royal Society of Chemistry 2015 A Sensitive Electrochemical Sensor for Direct Determination of Phoxim in Food Samples Based on Electrodeposition of Reduced Graphene Oxide-Gold Nanocomposite on Glass Carbon Electrode 1 1,2* 3 4 Yuhong Zheng , Li Fu , Aiwu Wang , Wen Cai Supplementary Materials Figure S1. Molecular formula of phoxim. Figure S2. Pulsed electrodeposition mode for the deposition of RGO on GCE. Figure S3. SEM image of RGO/Au nanocomposite with lower magnification. Figure S4. A possible electrochemical reaction mechanism of phoxim at the RGO/Au/GCE. Table S1. Comparison of the analytical performance of RGO/Au/GCE with previously reported phoxim determination method. Method LOD (μM) Linear range (μM) Reference AChE/ZrO /CHIT/GCE 1.3 6.6-440 1 2 Graphene/GCE 0.008 0.02-2 2 P3MT/NGE/GCE 0.0064 0.2–2.0 3 RGO/Au/GCE 0.003 0.01– 10 This work Table S2. Summary of interference study of phoxim determination using RGO/Au/GCE. Interference species RSD(%) Interference species RSD(%) Na+ 0.66 Ascorbic acid 4.18 Zn2+ 1.20 Uric acid 2.01 Fe3+ 3.66 Malathion 1.45 Ca2+ 1.02 Methyl isofenphos 0.86 K+