大学基础化学复习提要（A review of basic chemistry in Universities）.docVIP

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大学基础化学复习提要（A review of basic chemistry in Universities）.doc

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大学基础化学复习提要（A review of basic chemistry in Universities）.doc

大学基础化学复习提要（A review of basic chemistry in Universities） A review of basic chemistry in Universities ------------------------------------ The main content of the course 1. basic principles of Chemistry * thermochemistry * chemical equilibrium * rate of chemical reaction Principle and application of 2. chemical equilibrium Acid base equilibrium and acid-base titration * precipitation equilibrium * redox equilibrium and titration * coordination equilibrium and complexometric titration 3. material structure * atomic structure * molecular structure 4. element chemistry * properties of non metallic elements and compounds Properties of transition elements and compounds ---------------------------------------- Basic test questions Judgment questions, choice questions, filling questions and calculation questions Chapter 1 focuses on thermochemistry: State and state functions Calculation Attention point: 1, thermodynamic standard state: under the P theta (101325Pa) pressure, ideal gas, liquid and solid pure substance, 1mol * L-1 concentration solution. 2, when understanding, the most stable single substance refers to: C (graphite), Cl2 (g), Br2 (L), I2 (s), etc.. 3, 1) Gasss law: The thermochemical equation is added and reduced, and the corresponding addition is also reduced. At 1 and 298.15K, the standard molar enthalpy of formation of NaCl (s) is -770.8kJ? Mol-1 due to the Na+ (g) +Cl- (g) = NaCl (s) = -770.8kJ? Mol-1. (x) Standard molar enthalpy of reaction: enthalpies of formation of 1mol compounds from the most stable single substance. In this case, Na+ (g) +Cl- (g) is not the most stable single substance. Case 2, reaction Na2O (s) + I2 (g) -2NaI (s) + O2 (g) is (C) (A) 2 (NaI), (s) - (Na2O, s) (b) (Nai, (s) - (Na2O, (s) - (I2, g) (c) 2 (Nai, (s) - (Na2O, (s) - (I2, g) (d) (Nai, (s) - (Na2O, s) 例3、已知 Zn (s) + O2 (g) = ZnO (s) = 1 - 351.5 kJ? Mol - 1 (1) Hg (L) + O2 (g) = HGO (s) 2 = - females kJ? Mol - 1 (2) Zn (s) + HGO (s) = ZnO (s) + Hg (L) (3) 的3为 = - 260.7 kJ? Mol -