2-白炭黑轮胎加工所面临的挑战 范汝良.pptVIP

15. Januar 2003 Steger - Silica Tread I Challenges for Silica Tread Processing 白炭黑轮胎加工所面临的挑战 Dr.Lothar Steger /范汝良 Rhein Chemie Rheinau GmbH 莱茵化学（青岛）有限公司 Why silica compounds ?为何要发展白炭黑胎面？ By applying silica instead of carbon black in tire tread compounds the following results can be achieved : 用白炭黑代替炭黑具有如下优越性能： much lower rolling resistance of the tire 轮胎滚动损失降低很多 much better ice and snow performance 抗冰滑和抗雪滑行能优越很多 much better wet skid behaviour 抗湿滑性能改善很多 at similar tread wear patterns 具有相近的耐磨性 Benefits of Silica Technology vs. Carbon Black白炭黑技术优势与炭黑比较 Properties of Silica with respect to Carbon Black 白炭黑与炭黑的性能对比 Disadvantages of current silica technology 目前白炭黑技术的缺陷 1. Difficult to mix highly loaded silica compounds 高填充白炭黑胶料门尼粘度较高难于加工 2. Long mixing cycles increase mixing costs 长时间返炼/混炼，增加混炼成本 3. Temperature peaks during mixing lead to scorch problems; 混炼温度高，易导致焦烧; 4. Parts of silane are absorbed in porous silica getting inefficient; 多孔的白炭黑吸收部分硅烷偶联剂，导致效率降低; 5. Manufacturers need to buy more powerful equipment. i.e. intermeshing rotors. 加工者必须购买功率更高的设备，如：互齿式转子 (GKE密炼机) Challenges for Silica Tread Processing  白炭黑轮胎加工所面临的挑战 1. Good Dispersion of High Dosage Silica 高填充白炭黑的良好分散 2. Activation and Silanization of Silica 白炭黑的活化和硅烷化反应 3. Coupling Reaction between Diene Silica and Rubbers 白炭黑与二烯烃橡胶之间的偶联反应 4. New Curing Systems 新型硫化体系 5. More Powerful Equipment. i.e. intermeshing rotors. 功率更高的设备，如：互齿式转子 (GKE密炼机) ‘OEM’ Products Development for Silica Tire白炭黑轮胎所需的配套产品开发 用于白炭黑的高效分散剂—提高白炭黑的分散性 Aktiplast GT Aktiplast ST Aflux GE1837 白炭黑的有效硅烷偶联体系—提高白炭黑的硅烷化反应程度和提高白炭黑与二烯烃橡胶的偶联反应程度 Si-69/Si-75 Silane + SASD 适合于高用量白炭黑的新型硫化体系 二烷基二硫代磷酸锌 Processing Promoters for Tire Compound Processing用于轮胎胶料的加工助剂 Dr.Lothar Steger /范汝良 Rhein Chemie Rheinau GmbH 莱茵化学（青岛）有限公司 Processing Promoters : Definition加工助剂的定义 Division of Processing Promoters according to Their Chemical Composition 根据化学组成对加工助剂的分类 Division of