绪论与第一章气体双语.pptVIP

Introduction 0.1. What is Physical Chemistry? Physical chemistry is a discipline that studies the principle and methods of chemistry, and the most general law and theory of chemical systems. Physical chemistry investigates the inbeing of chemistry, and utilizes mathematical and physical methods and introduces different experimental means to investigate chemical laws. 0.2. The contents of physical chemistry (1) Thermodynamics (热力学） that studies the transformation of energy in the change of matters （ p、V、T、phase and chemical changes), and the direction and limit of energetic effects (work, heat). Thermodynamics concerns the law of energy conservation and the law of matter equilibrium. (2) Quantum mechanics （量子力学） that studies moving states of micro-systems. In elementary application, the Schr?dinger equation is set up for the system and then solve either analytically or, in many-practical systems, numerically, with due note of the boundary conditions . (3) Statistical mechanics （统计力学） that studies the average behavior of large assemblies of particles. Statistical mechanics is the theory in which the properties of macroscopic system are predicted by the statistical behavior of their constituent particles. Branches of physical chemistry： Quantum chemistry（量子化学） Structural chemistry(结构化学) Catalytic chemistry(催化化学) Electrochemistry(电化学) Photochemistry(光化学) Colloid Chemistry(胶体化学) Thermochemistry(热化学) The development trend ofphysical chemistry ? From macro systems to micro systems ? From bulk to surface ? From static to transition ? From qualitative to quantitative ? From equilibrium to non-equilibrium 0.3 The study methods of physical chemistry (1) Macroscopic method It is thermodynamic method. Thermodynamics concerns macroscopic system that consists of large amount of particles. The peculiarity of this method consists in that the method does not care the microscopic structure of particles inside matters, but deals with only the macroscopic properties bef