Catalyic Transformation of Ethylbenzene over Y Zeolite 催化转化乙苯在Y沸石.docVIP

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Catalyic Transformation of Ethylbenzene over Y Zeolite 催化转化乙苯在Y沸石.doc

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Catalyic Transformation of Ethylbenzene over Y Zeolite 催化转化乙苯在Y沸石

Catalytic Transformation of Ethylbenzene over Y- Zeolite Based Catalysts Sulaiman Al-Khattaf Chemical Engineering Department, King Fahd University of Petroleum Minerals Dhahran 31261, Saudi Arabia Abstract Catalytic transformation of ethylbenzene (EB) has been investigated over USY-zeolite based catalysts in a novel riser simulator at different operating conditions. The effect of reaction conditions on EB conversion is reported. The USY catalyst (FCC-Y) was modified by steaming to form a significantly lower acidity catalyst (FCC-SY). The current study shows that the FCC-SY catalyst favors EB disproportionation more than cracking. A comparison has been made between the results of EB conversion over the lowly acidic catalyst (FCC-SY) and the highly acidic catalyst (FCC-Y) under identical conditions. It was observed that increase in catalyst acidity favored cracking of ethylbenzene at the expense of disproportionation. Kinetic parameters for ethylbenzene (EB) disappearance during disproportionation reaction over the FCC-SY catalyst were calculated using the catalyst activity decay function based on time on stream (TOS). Keywords: Ethyl benzene, Diethyl benzene, Cracking, disproportionation, fluidized-bed reactor, USY-zeolite, modeling, *Corresponding author. Tel.: +966-3-860-1429; Fax: +966-3- 860-4234 E-mail address: skhattaf@kfupm.edu.sa 1. Introduction: The catalytic disproportionation of ethylbenzene over zeolite based catalyst to produce isomers of diethylbenzene amongst other products has gained tremendous attention in recent years. This is due to the wide range of application of these compounds in a variety of industrial processes. For example, para - diethylbenzene which is the most important of the three diethylbenzene isomers is an important desorbent in adsorptive separation processes such as UOP Para-ex used for the separation of xylene isomers. Besides, it can be used as an intermediate in the production of p-divinylbenzene. Also it is an important mon