Titration Weak Acid by Strong Base过强碱滴定弱酸.pptVIP

Now- We need an indicator which changes near pH 8.72. At this point we need a Table of indicators. pH and Color Changes for some common Acid-Base Indicators: 14 12 10 8 6 4 2 pH Scale alizarin yellow Phenolphthalein bromthymol blue methyl orange methyl violet At a pH of 8.72, Phenolphthalein would be a good choice. Titration Curves (Part II): Weak Acid by Strong Base Let’s look at this type of Titration Curve: /links/AcidsBases/flash/titrateWeakAcidStrongBase.swf Several Important differences: --initially most of the weak acid is whole molecules NOT ions --the pH at equivalence point is NOT 7 Important Feature---  UNCHANGED: For equal volumes of acid solutions of the SAME molarity, the volume of base required to titrate to the equivalence point is independent of whether the acid is strong or weak. Calculating Titration Curve: Weak acid by a Strong Base What is the pH at each of the following points in the titration of 25 ml of 0.1 M H C-2H3O2 by 0.1 M NaOH --Before ANY NaOH added(initial pH) --After 10 ml 0.1 M NaOH added(before) --After 25 ml 0.1 M NaOH added(neutralization) --After 26ml 0.1 M NaOH added(after) Initial pH H C2H3O2 ----- H+ + C2H3O2 - 0.1M-x x x Ka = 1.8 x 10-5 = x2/ .1-x As2 x = 1.34 x 10-3 M = [H+ ] pH = 2.88 After 10 ml of 0.1M NaOH VNaOH MNaOH = 10 ml(0.1 M) = = 1.0 mmol OH - H C2H3O2 + OH ------ H2O + C2H3O2- init 2.5 mmol 1.0 mmol react -1.0 mmol -1.0 mmol +1.0 mmol after 1.5 mmol 1.0 mmol Calculation- H C2H3O2 ----- H+ + C2H3O2 - 1.5 mmol -x X 1.5 mmol +x(0.04 M) 1st calc. MHCl : 1.5 mmol/12.5 +10ml = 0.04 29M 2ndcalc. MNaOH: 1.0 mmol/12.5 +10 ml = 0.0286 M Ka = 1.8 x 10-5 = x (0.0286 M)/ 0.0429 M [H+]=x=2.7 x 10-5 pH = 4.58 Want to try Henderson -Hasselba