碱溶粉煤灰取硅工艺条件优化毕业论文.doc

碱溶粉煤灰提取硅工艺条件优化 学生姓名： 学生学号： 院 （系）： 生物与化学工程学院 年级专业： 08 环境工程 指导教师： 2012年5月 摘 要 本论文主要研究从粉煤灰中提取硅的机理及工艺。以攀枝花粉煤灰为原料，选用碱溶法溶出方式，考察了粉煤灰粒度、碱溶时间、碱溶温度、碱浓度、液固比等因素对氧化硅提取的影响。 本论文对粉煤灰，采用碱溶粉煤灰法研究制备二氧化硅，以粉煤灰、氢氧化钠为原料。常压下高浓度氢氧化钠溶浸粉煤灰提取二氧化硅过程中粉煤灰粒度、溶浸时间、氢氧化钠初始浓度、液固比、反应温度等因素对二氧化硅溶出率的影响。 结果表明：研磨后的200目粉煤灰在碱浓度为17.5mol/l、液固比1.5:1及130摄氏度溶浸时，反应8min，可使二氧化硅的溶出率达到最高。用此法处理粉煤灰提取硅，具有节能降耗的优点，为粉煤灰的开发与利用开辟了一条途径。 关键词：粉煤灰，氧化硅，碱溶法，溶出率  ABSTRACT This paper mainly studies the extraction of silicon from fly ash and the mechanism of the process. Panzhihua fly ash as raw materials, selection of alkali leaching, examines the fly ash particle size, alkali dissolution time, alkali solution temperature, alkali concentration, liquid solid ratio and other factors on the silicon oxide extraction effect. This paper on the fly ash, using fly ash in alkaline solution method of preparation of silica, fly ash, sodium hydroxide as raw materials. Under the pressure of high concentration sodium hydroxide solution leaching of fly ash silica extraction process of fly ash particle size, leaching time, sodium hydroxide concentration, liquid solid ratio, reaction temperature and other factors on the silica dissolution rates of. The results show that: after the grinding 200 heads of fly ash in alkaline concentration is 17.5mol / L, liquid solid ratio of 1.5:1 and 130 degrees C solution, reaction 8min, can make the silica dissolution rate reached the highest. Method for treatment of fly ash from silicon, has the advantage of energy saving, the development and utilization of fly ash has opened up a way. Keywords : fly ash, silicon oxide,alkali fusion , dissolution rate  目录 摘 要 I ABSTRACT II 1 绪 论 1 1.1 课题研究背景及意义 1 1.1.1 课题研究背景及意义 1 1.1.2 课题研究意义 2 1.2 国内粉煤灰的应用 2 1.2.1 粉煤灰混凝土 2 1.2.2 粉煤灰水泥 3 1.2.3 粉煤灰制砖 3 1.2.4 粉煤灰筑路 3 1.2.5 粉煤灰选取漂珠 3 1.2.6 粉煤灰改良土壤 3 1.3 国外粉煤灰利用途径和工艺 3 1.3.1 粉煤灰处理矿山酸性废水 4 1.3.2 粉煤灰作回填材料 4 1.4 粉煤灰综合利用发展前景分析 4 1.5 课题研究思路 5 2