疏水接枝丙烯酰胺聚合物驱油的合成及性能研究博士毕业论文.doc

疏水接枝丙烯酰胺聚合物驱油剂的合成及性能研究 Synthesis and Property Studies on Hydrophobically Graft Copolymer of Polyacrylamide Flooding Agents 学科专业： 油气田开发工程 研究方向： 提高采收率与采油化学 摘 要 聚合物驱是三次采油提高采收率的重要驱油技术，新型聚合物驱油剂的研发受到人们越来越多的关注本文具有表面活性的结构单元本文N-苄基-N-辛基丙烯酰胺（BOAM）和N-苄基-N-十二烷基丙烯酰胺（BDAM）2-丙烯酰胺基十二烷磺酸钠(NaAMCl2S) 以及辛基酚聚氧乙烯醚丙烯酸酯（OP-10-AC）AM-NaA-BOAM、AM-NaA-BDAM、AM-NaA-AMC12S-BOAM、AM-NaA-OP10AC-BOAM，并用FTIR红外光谱表征了聚合物的结构，用稀释外推法测定了聚合物的相对分子质量。疏水接枝共聚物的胶束聚合的反应条件，因素单体的投料比、单体总浓度、引发剂浓度、引发温度、表面活性剂以及各种添加剂等对产物的特性黏数和增黏性能的影响，疏水接枝共聚物疏水接枝共聚物的最佳聚合条件 本文用Brookfield DV-II型黏度计和MCR301型流变仪研究了疏水接枝共聚物溶液的性质，考察了聚合物浓度、NaCl浓度、剪切作用及测试温度等因素对疏水接枝共聚物的增黏性能的影响在亚浓溶液中，当聚合物浓度超过临界缔合浓度（C*）时，溶液的表观黏度显著增大，表现出良好的增稠性能疏水接枝共聚物具有良好的黏弹性，聚合物溶液的储能模量（G′）大于损耗模量（G′′），主要以弹性为主。 本文本文通过室内物理模拟驱油实验，疏水接枝共聚物AM-NaA-OP10AC-BOAM的驱油性能，结果表明，水驱后，HPAM驱能提高采收率1.66%，而接枝共聚物驱可以提高采收率18.03%，比HPAM驱油剂的原油采收率高.37个百分点 关键词： 疏水接枝共聚物，聚丙烯酰胺，胶束聚合，流变性，黏弹性，耐温抗盐，聚合物驱Synthesis and Property Studies on Hydrophobically Graft Copolymers of Polyacrylamide Flooding Agents Abstract Being a very important oil flooding technique for EOR, polymer flooding is used widely in many oilfields, more and more interests are growing in developing novel polymer flooding agents. In this paper, a series of hydrophobically graft polyacrylamides have been synthesized by using molecular design. Two novel disubstituted hydrophobic acrylamide comonomers containing alky and aryl groups have been incorporated into the polymer chains with the object of improving the thermal stability and viscosity of polymer due to the rigid planar structure of bezene ring and the double tail structure. Furthermore, two surface-active monomer were also incorporated, in order to improve the surface activities of the polymers, and the hydrophilic monomer containing sulfonic group was also used to improve the solubility of polymer. In this paper, two novel disubstituted hydrophobic acrylamide comonomers, N-benzyl-N-octylacrylamide (BOAM) and N-benzyl-N-dodecylacrylamide (BDAM) have been synthesized, and two surface active monom