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摘 要 本研究将适量锌离子(II)取代镁铝水滑石中的镁离子(II),以及将一定量的8-羟基喹啉(8-hydroxyquinoline)分散于镁铝水滑石层间的亲油性阴离子中,使与其板层表面上的锌离子配位,经共沉淀法,合成、组装得到一类迄今未见报道的具高荧光性的类水滑石(Zn-HTLC)荧光材料.采用荧光光谱、红外光谱、紫外光谱、X射线衍射和热分析等对其进行了表征.研究表明,这种类水滑石在紫外光下可发出强烈的蓝绿色荧光(501 nm),荧光强度高达4.5×105a.u.,说明锌离子(II)分散于类水滑石的氢氧化镁板层中,可有效防止发光结构单元的荧光猝灭,而且溶于层间阴离子中的配体与板层上的锌离子(II)配位所形成的特殊组装结构,增强了发光中心的不对称性,也是其具有高荧光性的可能原因.热分析结果显示,这种类水滑石耐热性强,有望应用于各种功能性荧光材料. 关键词：类水滑石;荧光;8-羟基喹啉锌;插层;组装;超分子 Abstract A hydrotalcite-like compound in which magnesium(II)was partially substituted by zinc(II)in thehydrotalcite-like layers and 8-hydroxyquinoline was dispersed into the anions in the interlayer region wassynthesized by a coprecipitation method.Each Zn2＋ion in the layers was coordinated by 8-hydroxyquino-line through the oxygen and nitrogen atoms,making a strong-fluorescentZn-containing hydrotalcite-likecompound (Zn-HTLC) that has never been reported before.The sample has been characterized by X-raypowder diffraction,FT-IR techniques,thermogravimetric analysis,UV/Vis spectrography,fluorescence spectrum,and its composition and structure were determined.It was found that the Zn-HTLC could radiate strong light(501 nm)under ultraviolet radiation,demonstrating that the zinc(II)dispersed in the hydrotal-cite-like layers can prevent the fluorescence quenching effect efficiently.The Zn2＋ion in the layers was co-ordinated by the ligand in the interlayer region,forming a special self-assembly structure that may enhancethe fluorescence intensity.Otherwise,the result of TG-DSC measurement clearly shows the enhanced ther-mal stability of the Zn-HTLC compared with that of Mg-Al hydrotalcite.The Zn-HTLC may become apromising candidate for the luminescent functional materials. Keywords:hydrotalcite-likecompound;fluorescence;8-quinolinolatozinc;intercalation;assembly; supramolecule 目 录 摘 要 I 1 文献综述 3 1.1类水滑石类化合物的概述 3 1.1.1类水滑石的组成与结构特征 3 1.1.2 类水滑石的性质 3 1.2.3类水滑石在荧光方面的应用及发展前景 4 1.2 类水滑石的制备方法 5 1.3本论文的研究内容及意义 6 1.4研