弛豫铁电体的制备.docVIP

BaXSr(1-X)TiO3 弛豫铁电体的制备 The preparation of BaXSr(1-X)TiO3 relaxor ferroelectrics 作者：杨丽 指导教师：曹万强 摘 要 本论文结合陶瓷的研究情况，用传统的固相反应法制备了BaXSr(1-X)TiO3 陶瓷体。主要选择配方制备了x = 0.5和x = 0.8的BaXSr(1-X)TiO3陶瓷体。 制备的工艺过程如下：计算、称量 --→ 球磨 --→ 干燥--→ 研磨--→ 预烧 --→ 球磨 --→ 干燥 --→ 造粒 --→ 成型 --→ 烧结 --→ 被银 。然后用数字电桥测量其介电性能。 制备工艺条件表明，掺杂质量百分比为0.2%的Nb2O5的Ba0.5Sr0.5TiO3的最佳烧结温度为1280℃；而Ba0.8Sr0.2TiO3的最佳烧结温度为1275℃。Ba / Sr的比例越大，陶瓷的收缩越小，致密性越好。Ba0.5Sr0.5TiO3和Ba0.8Sr0.2TiO3 都具有良好的铁电性和较好的弛豫性。由测试结果可以看出，他们都具有高的介电性，相对低的烧结温度。但他们的介电常数虽然很大(Ba0.8Sr0.2TiO3 的εr′max = 210.5×103)，其介电损耗相对也很大。特别是Ba0.8Sr0.2TiO3 ，损耗尤其大（Ba0.8Sr0.2TiO3 的tanδmax= 1.36）。虽然BST具有较好的弛豫性, 但是Ba0.8Sr0.2TiO3 的损耗温谱与一般弛豫介质的温谱出现了反常：εr＂和tanδ的极值温度随频率增加向低温方向移动。由εr′—— f 、εr＂—— f 、εr′—— T和εr＂—— T的关系图了解到，A位取代的复合钙钛矿结构BST仍具有和铅系B位取代陶瓷相类似的弛豫性。 关键词：固相反应 烧结温度 弛豫性 介电性 Abstract BaXSr(1-X)TiO3 ceramic were synthesized by conventional solid state reaction.We mainly studied the fabrication and the relaxation of BaXSr(1-X)TiO3 with x=0.5 and x=0.8. The fabrication process is displayed as following: weigh the chemical powder -→ ball mill -→ dry the slurry -→ milled -→ calcine -→ball mill-→ dry the slurry -→ milled -→ punched -→ sinter -→ silver plating. Then we tested the dielectric properties of the BST specimen with a Digital Electric Bridge. The study on preparation technology shows the best sintering temperature of Ba0.5Sr0.5TiO3 and Ba0.8Sr0.2TiO3 intermingling with wt 0.2% Nb2O5 are 1280℃ and 1275℃ respective. The higher the Ba / Sr molar ratio ,the biger shrinkage and dense the ceramic is. Both Ba0.5Sr0.5TiO3 and Ba0.8Sr0.2TiO3 have good dielectric properties and good relaxor properties.As the study we concluded that although the BST have high dielectric constant（Ba0.8Sr0.2TiO3：εr′max = 210.5×103）and low sintering temperature , their dielectric loss tangents is too high ,especially for the Ba0.8Sr0.2TiO3（tanδmax= 1.36） . And the A-site substitution Perovskite BST ceramic has a similar relaxor properties with the B-site substitution lead ceramic .