敬賀 朱秋龍榮膺本會55屆理事長.docVIP

摻雜鉑金屬先後順序對TiO2奈米纖維光觸媒由乙醇產氫效率的影響* Effect of Pt loading order of TiO2 nanofiber on the efficiency of H2 generation* 林 秋 薰1 ■ 劉 志 緯2 * 九十八年十月二十二日在本會九十八年年會宣讀之論文 彰化師大化學系 1教授 2碩士生 利用含浸法製備的含1 wt% Pt金屬的TiO2奈米纖維光觸媒，由於含浸Pt之先後次序不同，分別標示為PtHTN與PtB。前者直接把H2PtCl6含浸在鈦酸(H2Ti3O7)奈米纖維上，然後高溫鍛燒(在300和600℃之間)，於150℃把Pt加氫還原成奈米金屬顆粒。而後者是先把鈦酸奈米纖維先鍛燒成TiO2(B)奈米纖維(同樣在300和600℃之間)，再含浸H2PtCl6 XPS (X-ray photoelectron spectroscopy)和SAT-TPR (Sub-ambient temperatureprogrammed reduction)的結果指出，PtB較高的光催化活性是由於觸媒表面上Pt顆粒濃度較高，且PtB之電子傳導性和還原性較佳。這些導電性和產氫能力的差異，乃是因為摻雜順序的不同，經鍛燒氧化/加氫還原的前處理後，兩種觸媒內Pt和TiO2奈米纖維表面間的作用力產生極大的差異:High resolution TEM顯示，PtHTN內的Pt顆粒強力的附著於奈米纖維表面之上，而PtB內之Pt則無。 關鍵詞： 二氧化鈦、奈米纖維、光觸媒、氫氣、鉑 TiO2 nanofibers loaded with 1wt % Pt metal at different stages of wet impregnation procedure are denoted as PtHTN catalyst and PtB catalyst. PtHTN catalyst was prepared by impregnating hydrogen trititanate nanofibers (H2Ti3O7, HTN) directly with H2PtCl6, calcining at temperatures between 300 and 600℃, and then reducing at 150℃ by hydrogen. PtB catalyst was prepared by calcining HTN nanofiber at temperatures between 300 and 600℃ to yield TiO2(B) nanofiber, and impregnating this TiO2 support with H2PtCl6. The support was then calcined and reduced as for PtHTN to produce PtB Photocatalyst. Although physical properties of PtHTN and PtB catalysts are quite similar, the optimized H2 yield using PtB catalyst in the photocatalytic dehydrogenation of ethanol was 1.86 times that of PtHTN catalyst. XPS and Sub-ambient temperature TPR revealed that the higher activity of PtB The specific Pt impregnation order in the PtHTN catalyst precipitated in a strong interaction between the Pt nanoparticles and the TiO2 nanofiber surface that was absent in the PtB catalyst. HRTEM also showed the particular microstructure at the Pt-nanofiber interface responsible for the marked difference between the electronic properties and photocatalytic activities of the two catalysts. Key words: TiO2, nanofiber, Photocatalyst, hydrogen, Pt 壹、前　言 由於全球石油的