tdi改性环氧树脂预聚体活泼氢性固化剂及涂层的分析-analysis of active hydrogen curing agent and coating of tdi modified epoxy resin prepolymer.docxVIP

AbstractBisphenol A type epoxy resin is cheap and has good adhesion, mechanical properties and corrosion resistance. So it widely used in coatings, construction, adhesives and other industries. The same time, coal tar as a byproduct of coking , has excellent properties like aging resistance, waterproof, antiseptic and anti-microbial erosion to make it used for severe anti-corrosion. This paper based on the characteristic that isocyanate groups easy to react with hydroxyl, uses TDI and epoxy as raw material synthesized a new curing agent which can cure macromolecules with active hydrogen groups. By experiments determined the formula and process of preparing the curing agent. After removing water, coal tar as a film-forming material to prepare main anti-corrosion paint by adding solid fillers and additives. Then using homemade curing agent and coal tar main paint to confect anti-corrosion coatings, determined the coating formulations, studied coating combination property.The optimization formulation and process of synthesis the curing agent are as follows: R value (the molar ratio of TDI and epoxy -OH) 1.5, 1.2% of the antioxidants, the reaction insulation 90°C , the reaction time is 5h. Finally the performance of the curing agent is better, viscosity and -NCO content are respectively 28.2 mPa?s and 3.06%. The infrared spectroscopy characterization indicates that the reactants epoxy hydroxy peaks disappeared, -NCO characteristic peak intensity decreases, products have urethane groups. This shows that TDI successfully modified epoxy resin, and synthesized terminal -NCO prepolymer, but epoxy group had no change. TG/DTA tests show that the thermal stability of modified prepolymer is better than the epoxy resin.MS software simulate the reaction of TDI and epoxy resin, calculate the activation energy of different molecular weight epoxy resin (n = 1, 2) hydroxyl react with different positions -NCO of TDI. From the results know, the epoxy resin of low molecular weight (n = 1