ti-v基合金相结构及储氢性能研究-phase structure and hydrogen storage performance of ti - v base alloy.docx

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ti-v基合金相结构及储氢性能研究-phase structure and hydrogen storage performance of ti - v base alloy.docx

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ti-v基合金相结构及储氢性能研究-phase structure and hydrogen storage performance of ti - v base alloy

摘要the contents of secondary phase increase after heat treatment. The activation performanceand kinetic properties are improved greatly after heat treatment. DSC curves indicate two endothermic peaks between 550-650 K and 650-750 K which are related to thetransformation of VH2.01 hydride to distortion BCC structure and transformation of distortion BCC structure to the original BCC structure. DSC curves and TPD curvesindicate that the hydrogen release temperature is lower after heat treatment which is in accordance with the kinetics results.Keywords:Ti-Vbasedalloys;hydrogenstorageproperties;heattreatment; absorption/desorption kinetics.中 This project is financially supported by the National Natural Science Foundation of China ， the Natural Foundations of Guangxi Province (2012GXNSFGA060002 201201ZD009) and Guangxi Experiment Center Of Information Science .目录目录摘要.......................................................................................................................................IAbstract..................................................................................................................................II目录....................................................................................................................................IV第一章绪论........................................................................................................................ 1§1.1 储氢材料的机理..................................................................................................... 2§1.1.1 储氢材料的热力学机理.................................................................................. 2§1.1.2 储氢材料的动力学机理.................................................................................. 4§1.2 储氢合金类型......................................................................................................... 5§1.2.1 AB5 型5§1.2.2 AB 型6§1.2.3 AB2 型691.2.4 A2B 型6§1.3 钛钒基储氢合金............................