苯乙烯二聚体的合成及变温红外光谱分析-synthesis of styrene dimer and analysis of variable temperature infrared spectroscopy.docxVIP

ABSTRACTIn order to investigate the change of polymer structure, Fourier Transform infrared spectroscopy(FTIR) is widely applied for its high sensitivity. It can also be used to study the glass transition behavior of the polymer system. The configuration and conformation of polystyrene (PS) are very complex and hard to be confirmed, so a simplified model of polystyrene, especially styrene dimer is needed for auxiliary study.In this paper, styrene dimer was generated via Wurtz coupling reaction and Kumada coupling reaction and then the product was extracted by vacuum distillation and column chromatography. The structures and properties were characterized via Mass Spectrometry (MS), Gas Chromatography (GC) and N uclear Magnetic Resonance (NMR).1,4-diphenylbutane was successfully synthesized by Wurtz coupling reaction with two different catalytic systems. We changed the time and temperature, and analyzed the effect and GC yield. When the reaction time and temperature was 16hours and 25℃, the results showed that the product with β-bromine ethyl benzeneacted as raw material had the highest GC yield. FTIR was used to verify the product and the assignments of infrared peaks were analyzed. It was confirmed that 1,4-diphenylbutane can be used as PS model molecule. We also found several changes of 1,4-diphenylbutane at various temperatures by analyzing its infrared spectra.1,3-diphenylbutane was successfully synthesized by Kumada cross couplingreaction. We also compared the effect and GC yield of experiments using two different catalytic systems. Two different catalytic systems were used in the experiment and the results suggested that the experiment with Fe(acac)3/TMEDA/HMTA performed better.KEY WORDS：Styrene Dimer, Wurtz Coupling, Kumada Cross Coupling, FTIR目录第一章 绪论..................................................................................................................11.1 引言.............................................................................