不同氮源处理mtio3m=zn,sr光催化剂的制备及光降解性能研究-preparation and photodegradation of mtio 3m = zn, sr photocatalyst treated with different nitrogen sources.docxVIP

AbstractPerovskiteoxide(suchasZnTiO3andSrTiO3)hasgoodphotocatalysisactivity,largequantumefficiencyandsoon.Itisapromisingphotocatalyticmaterial.However,itwillnotbeabletoachievethephotoexcitationinvisiblelight.Sointhispaper,wepreparethephotocatalystwhichhasaresponseperformanceofvisiblelightthroughprocessingmethodsofdifferentNsources.NH3isusedastheNsourcetoprocesstheprecursorofZnTiO3topreparethephotocatalystofTiO2-x:Zn,N.Ureaasnitrogensource,CNpolymer,pureSrTiO3,CN/N-SrTiO3andCN/SrTiO3weresynthesizedbyhightemperaturereaction.ThepowdersampleswerecharacterizedbyXRD,SEM,TEM,UV-Vis,XPSandPL.TheresultsofRh-Bdecompositionindicatethesamplesphotocatalyticability.PowderofZnTiO3precursorwerefirstlysynthesizedbysol-gelmethod.Thenitco-treatmentwithNH3andH2athightemperature,getTiO2-x:Zn,N.TheXRDandTEMpatternofsampleTitaniumdioxideconsistedwellwiththestandardanataseTiO2:Zn,NandrutileTiO2:Zn,N.XPSresultssuggestedthat0.4%ofthenitrogenatomsand0.9%ofthezincatomsweredopedintoTiO2throughthesyntheticmethod.Furthermore,theresultsofthedecompositionofRhodamineB(Rh-B)undervisiblelightrevealedthatRh-Bwasdegradationrateof96.6%within120min.CNpolymerpreparedbyconventionalsolid-statereaction.Ithasfavorablepropertiessuchassimplesynthesis,highstability,innocuousnessandphotoca-talyticabilityundervisiblelight.ItisshownbyXRDthatCNpolymerisnon-crystal.TheresultsofRh-Bdecompositionindicatethesamplesphotocatalyticability.Furthermore,theeffectofCNpolymeronthecrystalstructure,micromorphologyandenergybondstructureofcarriersandthephotocatalyticabilitywereanalyzedsystematically.Inthispaper,CN/N-SrTiO3andCN/SrTiO3weresynthesizedbypolymer-izablecomplexandmechanicalgrindingmethodreaction,respectively.XRDshowthatSrTiO3iscubic.CNpolymerdoesnotchangethecrystalstructureofN-SrTiO3andSrTiO3butcoveredthesurfaceofthemfromSEMpictures.WhenmixtureofCNpolymerandSrTiO3sinteredat400°C,noevidencefromXPSconfirmednitrogendopant.PhotodegradationresultsindicatethatCNpolymerhasgreateffectonphotocatalyticability,whichmadeRh-Bdecompose