超临界水冷堆堆芯候选材料腐蚀性能分析-corrosion performance analysis of candidate materials for supercritical water cooled reactor core.docx
超临界水冷堆堆芯候选材料腐蚀性能分析-corrosion performance analysis of candidate materials for supercritical water cooled reactor core
实验表明,静态腐蚀中温度对材料的腐蚀增重影响很大,所有的候选材料在 600℃时的腐蚀增重最为严重;在动态水腐蚀中,温度只 对 304NG 不锈钢的腐蚀增重影响显著,而对其他材料影响不大。在 相同的温度下,材料在动态水中的腐蚀增重比在静态水中的增重大, 表明流动水能够加速材料的腐蚀。总之,在材料表面形成一种致密、完整、稳定的保护性氧化膜对 于材料抵抗超临界水的腐蚀极其关键。Cr、Al 元素是材料形成稳定 性氧化膜的关键性元素,但在超临界环境下易形成挥发性的腐蚀产 物,导致氧化膜部分丧失保护作用而使腐蚀速度加快。根据目前的实验筛选结果,MA956、C276、AL-6XN 三种候选材 料在超临界环境下的耐蚀性能较为优异,有可能作为堆内构件和包壳 材料而在超临界水冷堆中得到应用。关键词:超临界水冷堆,耐蚀性能,氧化膜,腐蚀机理Corrosion behaviors of candidate materials for supercritical water-cooled reactorABSTRACTThe Supercritical water-cooled reactor (SCWR) is the only water-cooled reactor among the six Generation Ⅳ reactor concepts. It hasadvantages such a
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