大学化学ppt课件5对流层大气化学反应及光化学烟雾英文精编整理.pptVIP

Section 5 Chemical reaction in troposphere; Clean atmospheric constituents in troposphere is shown in talbe1. Carbon dioxide has been increasing in concentration during this century, mostly through the burning of fossil fuels such as coal and petroleum products. Trace constituents may vary in concentration in different parts of the atmosphere and in different parts of the globe.;3. Source and collection of atmospheric constituents and gaseous circulation;4. Important light absorption substances;4.2 Photolytic reaction of O3, HNO2, and H2O2;4.3 Photolytic reaction of HCHO and CH3CHO;O3 +hγ(λ≤320nm)→O(1D)+O2 O(1D)＋ H2O→2OH In pollution atmosphere, the following photochemical reaction is more important. HONO＋hγ(λ＜400nm)→OH＋NO H2O2＋hγ(λ＜360nm)→OH＋OH On average, the concentration of free radical OH is 7*105／cm3 on the globe. Seven times ten to the power of five;5.2 Source of free radical HO2;CH3CHO＋hγ→ CH 3＋HCO CH3COCH3＋hγ→CH3＋CH3CO RH＋O→ R＋ OH RH＋HO→R＋H2O CH3ONO十hγ→ CH3O＋NO CH3ONO2 ＋hγ→CH3O ＋ NO2 R+O2→RO2 ;5.4 Collection of free radical ;Section 6 Photochemical smog ;2. Daily change law of photochemical smog;3. Formation mechanism of photochemical smog ;4. Formation sign of photochemical smog ;（2） PAN (peroxy acetyl nitrate) RC(O)O2 + NO2 RC(O)O2NO2