LiIonBattery(LIB)-WelcometoCatalysisDatabase：锂离子电池(LIB)-欢迎催化数据库.pptVIP

LiFePO4 (LFP) Li Ion Battery (LIB) K.Devaki (CH09M001) Battery: Transducer which converts chemical energy into electrical energy and vive versa. Chemical reactions: Oxidation and reduction Free energy change of the processes appears as electrical energy. Primary battery-not rechargeable Secondary battery- rechargeable Battery Why Li-Ion Battery? Lead acid battery Appealing to industrial applications due to Reliable Inexpensive Disadvantages Low life cycle Low energy density (30 ~ 40 Wh/Kg) Ni metal hydride battery Appealing to hybrid electric vehicle applications due to Rechargeable No memory effect High power density High energy density Currently available battery capacity : 1.5 kWh Disadvantages Self discharge rates Recharge-ability : Basically, when the direction of electron discharge (negative to positive) is reversed, restoring power. Memory Effect : When a battery is repeatedly recharged before it has discharged more than half of its power, it will “forget” its original power capacity. Cadmium crystals have the memory effect (NiCd) J. Mater. Chem., 19 (2009) 5871 Schematic of Li Ion Battery The cathode half reaction (with charging being forwards) is: LiCoO2 ? Li 1-x CoO2 + xLi+ + xe- The anode half reaction is: xLi + + xe- + 6C ? Lix C6 Contains an anode, a cathode, an electrolyte and separator. Harnesses a set of reversible oxidation/reduction reactions. Li ion dissolved by a discharge reaction and returns to metallic lithium by a charging reaction Electrolyte provides for the separation of Li ions and electron transport. In a perfect battery the Li ion transport number will be unity. Cell potential is determined by ?G= -EF The electrode system must be both a good ionic and an electronic conductor. It is necessary to add an electronically conductive material such as carbon black. To hold the electrode together, a binder is also needed. Li Ion Battery Advantages Li has greatest electrochemical potential Lighter than