磁分子材料.PPT

分子磁体Molecule-Based Magnets 高 松 北京大学化学与分子工程学院 无机化学研究所 gaosong@ Main directions and hot points High Tc and Hard molecular magnets VII0.4VIII0.6[Cr(CN)6]0.86?3H2O (Tc = 310K， Nature,1995；Tc = 374K, JACS, 1999) MII{N(CN)2}2 (M = Cu, Ni, Co, Fe, Mn, Cr) (Hc=1.8T, 1998) High Spin Cluster, MQT, and Nano-wire Magnets Mn12Ac, Fe8 (Nature, 1993, 1996) Spin Crossover – From thermal to light driven Multifunction in one molecular system Magneto-optical, Photo-magnetic, Magnetic-Electrical Pure Organic Magnets Varied magnetic phases (1) magnetic brick (a) Varied magnetic phases (2) magnetic bric