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xpbni13nb23o3-1-xpbti0.6hf0.4o3三元压电陶瓷的制备与性能研究-xpbni 13 nb 23或3-1-xpbti0.6hf0. 4或1
AbstractPiezoelectricceramicisafunctionalmaterialwhichcanbemutualconversionbetweenmechanicalenergyandelectricalenergy,becauseofitsbettermechanicalpropertiesandstabilitypiezoelectricpropertiesetc,itcanserveasakindofimportantoptics,heat,mechanics,electricitysensitivefunctionalmaterials,widelyusedininformation,aerospace,electronicsandotherfields.Withtheresearchanddevelopmentofapplicationofpiezoelectricdevices,thepiezoelectricceramichighperformanceandwidemorphotropicphaseboundary,hightemperaturestabilityhavecausedmoreattentionofresearchers.Inthispaper,takingxPb(Ni1/3Nb2/3)O3-(1-x)Pb(Ti0.6Hf0.4)O3(hereinafterreferredtoasxPNN-(1-x)PTH)piezoelectricceramicsystemastheresearchobject.PreparingninedifferentPNNcontentofPNN-PTHpiezoelectricceramicsbythetechnologyofthesynthesisofthebodyafterprecursor,burn-in,moldingpressurepiece,sintering,burnpermeabilitysilverandpolarization,etc..ThisarticlecanensurethecomponentofmorphotropicphaseboundaryforxPNN-(1-x)PTHseriesinx=0.30-0.31.5throughXRDdiffractionpatternundernormaltemperature.WehaveindentifiedthecoexistenttemperaturerangebetweenrhombohedralandtetragonalphaseofvariouscomponentsthroughvariabletemperatureXRDdiffractionpattern.Whenx=0.25-0.28,twophasecoexistenceat105-150℃;Whenx=0.29,twophasecoexistenceat60-105℃;Whenx=0.30-0.315,twophasecoexistenceat30-105℃;Whenx=0.32-0.33,thereisnottwophasecoexistence.WecanseesectionsofpiezoelecticceramicPNN-PTHthroughtheSEMimage.Theporosityisverysmall,thegrainboundariesisclear,particledegreeis1-5μm,havinghighdensity.ThispaperstudiesthedifferentcontentofPNNpiezoelectricceramicxPNN-(1-x)PTHinfluenceontheperformance.ThroughthexPNN-(1-x)PTHpiezoelectricceramicperformancemeasurement,dataanalysis,theresultsareasfollows:xPNN-(1-x)PTHpiezoelectricceramicPNNalongwiththeincreaseofthecontentoftherelativedielectricconstantε33/ε0,dielectriclosstanδ,remainingpolarizationstrengthPr,piezoelectricconstantd33,electricalandmechanicalcouplingcoefficientKp,firstincreasemaximumthendecreases,whichxPNN-(1-x)PTHpiezoelectric
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