脉冲激光催化降解亚甲基蓝和2,4,5-三氯苯酚的实验分析-experimental analysis of catalytic degradation of methylene blue and 2,4,5 - trichlorophenol by pulsed laser.docx
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脉冲激光催化降解亚甲基蓝和2,4,5-三氯苯酚的实验分析-experimental analysis of catalytic degradation of methylene blue and 2,4,5 - trichlorophenol by pulsed laser
performancewasefficient.TheinitialoptimumdegradationconditionsforMBand2,4,5-TCPwereasfollowsrespectively:(1)thewavelengthofnanosecondpulsedlaserwas532nm,pulseenergywas135mJ,pulsefrequencywas10Hz,thequalityconcentrationsofMBandgoldnanoparticleswere4mg/Land11.6mg/Lrespectively;(2)thewavelengthofnanosecondpulsedlaserwas266nm,pulseenergywas19.4mJ,pulsefrequencywas10Hz,thequalityconcentrationsof2,4,5-TCPandgoldnanoparticleswere50mg/Land11.6mg/Lrespectively.ThehighestdegradationrateanddecolorizationrateofMBwasabout91%and94%respectivelyandthehighestdegradationrateof2,4,5-TCPwasabout85%undertheinitialoptimizedconditions.NanosecondpulsedlasercatalyticdegradationprocessesofMBand2,4,5-TCPfollowpseudo-firstorderkinetics.NanosecondpulsedlaserincreasesdegradationrateofMBand2,4,5-TCPperunitenergyabout25.7timesand34.6timeshigher,andthereactionrateof2,4,5-TCPalsoincreasesabout1.5times.Besides,thereisnearlynoreactionstartingtimefordegradationof2,4,5-TCPanditscatalyticconditionsaremoresimple.KEYWORDS:pulsedlaser;goldnanoparticles;catalyticdegradation;methyleneblue;2,4,5-trichlorophenol目录第一章绪论..................................................................................................................11.1工业废水中有机污染物降解的研究背景......................................................11.1.1工业废水中有机污染物的种类和来源................................................11.1.2工业废水中有机污染物的性质和危害................................................21.2工业废水中有机污染物的传统处理方法......................................................31.2.1生物法....................................................................................................31.2.2物理法....................................................................................................41.2.3化学法....................................................................................................41.3高级氧化法......................................................................................................51.4工业废水中有机污染物的脉冲激光催化降解.............................................
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