毕业答辩模板卟啉的合成与表征ppt课件.pptVIP

5,10,15-三苯基-20-{4-[S-(N-乙基氨基甲酰）硫]苯基}卟啉的合成与表征;提纲;1.卟啉及其衍生物研究的作用及意义;2.目标化合物的制备原理;3.合成过程中各阶段化合物核磁表征;1H NMR(CDCl3,TMS为内标,400MHz)，核磁共振峰与化合物（1）类似，不同之处是2.469ppm单峰消失，出现2.693ppm共振峰 (s, 3H, S(O)CH3)。;1H NMR(CDCl3,TMS为内标,400MHz)，δ0.793(s,3H,5-CH3)；1.277(s, 3H,5-CH3)；3.457(s, 1H, SH)；3.632(AB/2, 2H, J=10.8Hz, 4-或6-H)；3.754(AB/2, 2H,J=10.8H，6-或4-H)；5.337(s, 1H，2-H)；7.259-7.381(m, 4H, C6H4)。;1H NMR(CDCl3,TMS为内标,400MHz)，δ0.814(s, 3H,5-CH3)；1.090(t,3H,SCONHCH2CH3)；1.287(s,3H,5-CH3); 3.244-3.311(q,2H,SCONHCH2CH3);3.666(AB/2,2H,J=11.2Hz，4-或6-H); 3.786(AB/2, 2H, J=10.8Hz，4-或6-H)；5.267(br s, 1H, NH)；5.418(s, 1H,