水热法bi12sio20晶体形貌特征分析-morphology analysis of bi 12 sio 20 crystal by hydrothermal method.docxVIP

AbstractBi12SiO20(BSO),sillenitestructure,body-centeredstructureofthecubicsystem,spacegroupisI23.BSOhaspiezoelectric,electro-optic,photorefractive,photoconductive,magneto-optical,acousto-optical,opticalrotationandotherproperties.BSOiswidelyusedinopticalinformationprocessingandsensorelement.CzochralskihasbeenthemostcommonmethodtogrowBSOcrystal.Howevermanydefectshavebeenrevealedinthiscrystalgrowthmethod,particularlytoopticaluniformity.HydrothermalmethodhasbecomeaneffectivewaytogrowahighqualityBSOcrystal.BecauselackofthecriticaldefectinhydrothermalBSOcrystalascomparedtoCzochralskiandBridgman-Stockbarger.ThispaperfocusesonthecrystalmorphologyofthehydrothermalmethodBSO.Inthepaper,thehydrothermalBSOcrystalhastwodifferentcrystallineforms:thepolymorphsof{111}and{211};thepolymorphsof{100}and{110}.AanalysisoftwodifferentformsbyuseoftheBravaisrulesandtheDonnell-Hucktheory.Theanalysisindicatetherelativegrowthrateandexposuredegreeofeachfaces.Preliminarydiscussionofthecausesofchangeincrystalmorphologyoccurs,asolutionofthegrowingcrystaloversaturationchange,whichchangesthecrystalmorphologyhaveasignificanteffect.StudyonthecrystalmorphologyandsurfacestructuresoftwodifferentcrystallinehabitsofhydrothermalBSOcrystalswithDifferentialInterferenceContrastMicroscopeandinvertedmetallurgicalmicroscope．ThereareSpheroidgrowthhillockon{100}faces;lotsofgrowthhillocksandgrowthstepson{110}faces;growthhillocksandstriations-likegrowthstepson{211}faces;andgrowthhillocks,growthstepsandSpiralstriationthethreesymmetricalfeatureson{111}faces.ThemorphologyandsurfacestructuresofcrystalsofBSOcrystalistodeterminewithPBCbondsduringthecrystallizationprocess.TherearetwobasicbondsinBSOcrystal:[100]PBCand[111]PBC.Parallel{110}crystalfacehasthreePBCbonds,[100]、[111]and[111]PBC,anFface.ThemicromorphologyaccordwithFsurfacecharacteristics.Parallel{100}crystalfacehastwoPBCbonds,[001]and[010]PBC，anFface.ThemicromorphologyinlinewithFfacecharacteristics,too.Parallel{211}crystalfacehasone[111]PBCbonds,anSface.Themicromorp